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Communication Dans Un Congrès Année : 2016

On-Surface Synthesis of Phthalocyanine Compounds

E. Nardi
  • Fonction : Auteur
Mathieu Koudia
S. Kezilebieke
  • Fonction : Auteur
J. -P. Bucher
  • Fonction : Auteur

Résumé

In this chapter, we review the recent progress in the synthesis of phthalocyanine compounds at metallic surfaces under ultra-high vacuum conditions. Starting with tetra-carbonitrile-benzene molecules and magnetic atoms such as iron and manganese, we show that metal-organic coordination networks are formed at room temperature; then annealing at 500-600 K leads to the on-surface formation of phthalocyanine compounds. This reaction has been studied step-by-step by scanning tunneling microscopy and spectroscopy. The last part of this chapter is dedicated to the study of larger precursors functionalized with tetra-carbonitrile groups that react with copper atoms to form original polymers linked by phthalocyanine cores.
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Dates et versions

hal-01435240 , version 1 (13-01-2017)

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Citer

E. Nardi, Mathieu Koudia, S. Kezilebieke, J. -P. Bucher, Mathieu Abel. On-Surface Synthesis of Phthalocyanine Compounds. ON-SURFACE SYNTHESIS, 2016, Unknown, Unknown Region. pp.115-129, ⟨10.1007/978-3-319-26600-8_6⟩. ⟨hal-01435240⟩
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