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                <term xml:lang="en">Artificial ageing tests</term>
                <term xml:lang="en">iron gall ink</term>
                <term xml:lang="en">polymerisation degre </term>
                <term xml:lang="en">Arrhenius activation energy</term>
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              <p>Iron gall inks (IGI) were largely used for writing until the nineteenth century. Under certain circumstances, they provoke a substantial degradation of their cellulosic support.It was shown in a previous works thatc ombination  of oxygen and iron largely impacts cellulose chain breaking occurring in acidic conditions (pH 3–4). The present  study aims to study the kinetic of this degradation. It assesses the validity of Arrhenius law between 20 and 90°C taking advantage of the fast  depolymerization of IGI impregnated papers at room temperature and using two complementary tools: DP measurements and zero-span tensile strength. The ﬁrst one is sensitive enough to measure degradation at its very beginning, while the second is more appropriate for advanced stage of degradation. Similar activation energies (97± 2 kJ mol-1) were found viaDP and zero-span measurements, and reaction rates of IGI impregnated papers were 1–2 orders of magnitude aboveavailable data related to lignin-free acidic papers. These observations suggest a dominant hydrolytic mechanismthat involves directly or indirectly oxygen and iron.</p>
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