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Article Dans Une Revue Angewandte Chemie International Edition Année : 2015

Polyboramines for hydrogen release : polymers containing lewis pairs in their backbone

Résumé

The one-step polycondensation of diamines and diboranes triggered by the in situ deprotonation of the diammonium salts and concomitant reduction of bisboronic acids leads to the assembly of polymer chains through multiple Lewis pairing in their backbone. These new polyboramines are dihydrogen reservoirs that can be used for the hydrogenation of imines and carbonyl compounds. They also display a unique dihydrogen thermal release profile that is a direct consequence of the insertion of the amine–borane linkages in the polymeric backbone.

Dates et versions

hal-01412725 , version 1 (08-12-2016)

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Audrey Ledoux, Paolo Larini, Christophe Boisson, Vincent Monteil, Jean Raynaud, et al.. Polyboramines for hydrogen release : polymers containing lewis pairs in their backbone. Angewandte Chemie International Edition, 2015, 54 (52), pp.15744-15749. ⟨10.1002/anie.201508395⟩. ⟨hal-01412725⟩
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