N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2013

N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

Résumé

Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC.

Domaines

Chimie organique
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Dates et versions

hal-01397613 , version 1 (16-11-2016)

Identifiants

Citer

David Gatineau, Qiwu Zhao, Dennis P. Curran, Max Malacria, Emmanuel Lacôte, et al.. N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation. Dalton Transactions, 2013, 42 (20), pp.7458-7462. ⟨10.1039/c3dt32983f⟩. ⟨hal-01397613⟩
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