Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2008

Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation

Wenhua Bi
  • Fonction : Auteur
Nicolas Mercier

Résumé

The dehydration of a iodobismuthate hybrid built up from Bi4I16 clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI4 chains and 1D helical molecular chains, highlighting the templating effect of cations in the formation of iodobismuthate network.

Domaines

Chimie

Dates et versions

hal-01390611 , version 1 (02-11-2016)

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Citer

Wenhua Bi, Nicolas Mercier. Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation. Chemical Communications, 2008, 44, pp.5743 - 5745. ⟨10.1039/B812588K⟩. ⟨hal-01390611⟩
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