An experimental program is carried out to investigate the long term hydro-mechanical behavior correlated with chemical one of compacted soils with low concentration of Ca-bentonite and Ca-bentonite polymer mixture. The effect of prehydration on the hydraulic performance is compared to the polymer adding effect. All specimens are submitted to synthetic leachate (LS) under different permeation conditions. Several issues are studied: mechanical stability, hydraulic performance, chemical exchange of cations validated with microstructure observations. Scanning Electron Microscope (SEM) observations demonstrate two distinct behaviors: dispersive for Bentonite (B) and B with Polymer P1 (BP1) and flocculated for B with Polymer P2 (BP2). Direct shear tests show that bentonite adding increases the Soil (S) cohesion and decreases the friction angle. Polymer adding behaves similarly by maintaining the soil cohesion and increasing the friction angle. Hydraulic conductivity of prehydrated soil bentonite (SB) and direct permeation of polymer added soil bentonite are studied (SBP1 and SBP2). Hydraulic test duration are in range of 45 days to 556 days long. Prehydration allows to delay the aggressive effect of the LS in short term but seems to increase its negative effect on the hydraulic conductivity value in long term exposure. SB and SBP1 behave similarly and seem to act in the long term as a granular filler effect. SBP2 presents positive results comparing to the other mixtures: it maintains the hydraulic conductivity and the chemical resistance. Chemical analysis confirms that all specimens are subjected to Na+ dissolution and Ca2+ retention which are more pronounced for prehydrated specimen. The short term effect of prehydration and the positive effect of SBP2 are also confirmed.