Article Dans Une Revue RSC Advances Année : 2014

Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

Résumé

Fatty acid-based bis-cyclic 5-membered carbonates containing amide linkages were prepared from methyl 10-undecenoate. The reaction in bulk of these bio-based carbonates with a series of di-amines led to poly(hydroxyurethane amide)s with molar masses up to 31 000 g mol(-1). As expected, the so-formed bio-based thermoplastic poly(hydroxyurethane)s exhibit amorphous to semi-crystalline features with respect to the chemical structure of the monomers used.

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hal-01366356 , version 1 (22-11-2019)

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Lise Maisonneuve, Arvind S. More, Stéphanie Foltran, Carine Alfos, Frédéric Robert, et al.. Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s. RSC Advances, 2014, 4 (49), pp.25795-25803. ⟨10.1039/c4ra03675a⟩. ⟨hal-01366356⟩
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