Highly axial magnetic anisotropy in a N3O5 dysprosium(III) coordination environment generated by a merocyanine ligand
Résumé
A spiropyran-based switchable ligand isomerizes upon reaction with lanthanide(III) precursors to generate complexes with an unusual N3O5 coordination sphere. The air-stable dysprosium(III) complex shows a hysteresis loop at 2 K and a very strong axial magnetic anisotropy generated by the merocyanine phenolate donor.
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Highly axial magnetic anisotropy MC-Ln-Norel-Bernot-revised.pdf (754.4 Ko)
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