<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-01335356</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-26T21:36:50+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Natural sample fractionation by FlFFF–MALLS–TEM: Sample stabilization, preparation, pre-concentration and fractionation</title>
            <author role="aut">
              <persName>
                <forename type="first">Franck</forename>
                <surname>V.D Kammer</surname>
              </persName>
              <idno type="halauthorid">1039766-0</idno>
              <affiliation ref="#struct-67574"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Mohammed</forename>
                <surname>Baalousha</surname>
              </persName>
              <idno type="halauthorid">923216-0</idno>
              <affiliation ref="#struct-246705"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Mikael</forename>
                <surname>Motelica-Heino</surname>
              </persName>
              <email type="md5">b197371e82ab69827fb7558674838c74</email>
              <email type="domain">univ-orleans.fr</email>
              <idno type="idhal" notation="string">mikael-motelica-heino</idno>
              <idno type="idhal" notation="numeric">2530</idno>
              <idno type="halauthorid" notation="string">7279-2530</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/C-1930-2012</idno>
              <idno type="IDREF">https://www.idref.fr/170465772</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-6353-7524</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/C-1930-2012</idno>
              <affiliation ref="#struct-18404"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Philippe</forename>
                <surname>Le Coustumer</surname>
              </persName>
              <email type="md5">7b038fbef5a90058ac56e14833f37365</email>
              <email type="domain">u-bordeaux.fr</email>
              <idno type="idhal" notation="numeric">1045342</idno>
              <idno type="halauthorid" notation="string">1561016-1045342</idno>
              <affiliation ref="#struct-96900"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Mikael</forename>
                <surname>Motelica-Heino</surname>
              </persName>
              <email type="md5">b197371e82ab69827fb7558674838c74</email>
              <email type="domain">univ-orleans.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2016-06-21 21:01:08</date>
              <date type="whenWritten">2005</date>
              <date type="whenModified">2026-03-27 10:10:02</date>
              <date type="whenReleased">2016-06-21 21:01:08</date>
              <date type="whenProduced">2005</date>
              <ref type="externalLink" target="https://api.istex.fr/ark:/67375/6H6-XRPG89SL-N/fulltext.pdf?sid=hal"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="307705">
                <persName>
                  <forename>Mikael</forename>
                  <surname>Motelica-Heino</surname>
                </persName>
                <email type="md5">b197371e82ab69827fb7558674838c74</email>
                <email type="domain">univ-orleans.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-01335356</idno>
            <idno type="halUri">https://hal.science/hal-01335356</idno>
            <idno type="halBibtex">vdkammer:hal-01335356</idno>
            <idno type="halRefHtml">&lt;i&gt;Journal of Chromatography A&lt;/i&gt;, 2005, 1093 (1-2), pp.156-166. &lt;a target="_blank" href="https://dx.doi.org/10.1016/j.chroma.2005.07.103"&gt;&amp;#x27E8;10.1016/j.chroma.2005.07.103&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Journal of Chromatography A, 2005, 1093 (1-2), pp.156-166. &amp;#x27E8;10.1016/j.chroma.2005.07.103&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="SDE">Sciences De l'Environnement</idno>
            <idno type="stamp" n="BRGM">Bureau de Recherches Géologiques et Minières</idno>
            <idno type="stamp" n="GIP-BE">GIP Bretagne Environnement</idno>
            <idno type="stamp" n="BRGM-TEST">BRGM-TEST</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Natural sample fractionation by FlFFF–MALLS–TEM: Sample stabilization, preparation, pre-concentration and fractionation</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Franck</forename>
                    <surname>V.D Kammer</surname>
                  </persName>
                  <idno type="halauthorid">1039766-0</idno>
                  <affiliation ref="#struct-67574"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Mohammed</forename>
                    <surname>Baalousha</surname>
                  </persName>
                  <idno type="halauthorid">923216-0</idno>
                  <affiliation ref="#struct-246705"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Mikael</forename>
                    <surname>Motelica-Heino</surname>
                  </persName>
                  <email type="md5">b197371e82ab69827fb7558674838c74</email>
                  <email type="domain">univ-orleans.fr</email>
                  <idno type="idhal" notation="string">mikael-motelica-heino</idno>
                  <idno type="idhal" notation="numeric">2530</idno>
                  <idno type="halauthorid" notation="string">7279-2530</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/C-1930-2012</idno>
                  <idno type="IDREF">https://www.idref.fr/170465772</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-6353-7524</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/C-1930-2012</idno>
                  <affiliation ref="#struct-18404"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Philippe</forename>
                    <surname>Le Coustumer</surname>
                  </persName>
                  <email type="md5">7b038fbef5a90058ac56e14833f37365</email>
                  <email type="domain">u-bordeaux.fr</email>
                  <idno type="idhal" notation="numeric">1045342</idno>
                  <idno type="halauthorid" notation="string">1561016-1045342</idno>
                  <affiliation ref="#struct-96900"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">15209</idno>
                <idno type="issn">0021-9673</idno>
                <idno type="eissn">1873-3778</idno>
                <title level="j">Journal of Chromatography A</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">1093</biblScope>
                  <biblScope unit="issue">1-2</biblScope>
                  <biblScope unit="pp">156–166</biblScope>
                  <date type="datePub">2005</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1016/j.chroma.2005.07.103</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Steric elution</term>
                <term xml:lang="en">Pre-concentration</term>
                <term xml:lang="en">River colloids</term>
                <term xml:lang="en">SEM</term>
                <term xml:lang="en">TEM</term>
                <term xml:lang="en">MALLS</term>
                <term xml:lang="en">FlFFF</term>
              </keywords>
              <classCode scheme="halDomain" n="sde">Environmental Sciences</classCode>
              <classCode scheme="halDomain" n="sdu">Sciences of the Universe [physics]</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Two flow field flow fractionation (FlFFF) systems: symmetrical (SFlFFF) and asymmetrical (ASFlFFF) were evaluated to fractionate river colloids. Samples stability during storage and colloids concentration are the main challenges limiting their fractionation and characterization by FlFFF. A pre-fractionation (&lt;0.45 μm) and addition of a bactericide such as NaN3 into river colloidal samples allowed obtaining stable samples without inducing any modification to their size. Stirred cell ultra-filtration allowed colloidal concentration enrichment of 25-folds. Scanning electron microscope (SEM) micrographs confirmed the gentle pre-concentration of river samples using the ultra-filtration stirred cell. Additionally, larger sample injection volume in the case of SFlFFF and on channel concentration in the case of ASFlFFF were applied to minimize the required pre-concentration. Multi angle laser light scattering (MALLS), and transmission electron microscope (TEM) techniques are used to evaluate FlFFF fractionation behavior and the possible artifacts during fractionation process. This study demonstrates that, FlFFF–MALLS–TEM coupling is a valuable method to fractionate and characterize colloids. Results prove an ideal fractionation behavior in case of Brugeilles sample and steric effect influencing the elution mode in case of Cézerat and Chatillon. Furthermore, comparison of SFlFFF and ASFlFFF fractograms for the same sample shows small differences in particle size distributions.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="institution" xml:id="struct-67574" status="VALID">
          <idno type="ROR">https://ror.org/04bs1pb34</idno>
          <orgName>Technische Universität Hamburg = Hamburg University of Technology</orgName>
          <orgName type="acronym">TUHH</orgName>
          <desc>
            <address>
              <addrLine>Am Schwarzenberg-Campus 1, 21073 Hamburg</addrLine>
              <country key="DE"/>
            </address>
            <ref type="url">https://www.tuhh.de/tuhh/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-246705" status="INCOMING">
          <orgName>CDGA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-92972" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-18404" status="VALID">
          <idno type="IdRef">026362775</idno>
          <idno type="ISNI">0000000121846484</idno>
          <idno type="RNSR">195922846R</idno>
          <idno type="ROR">https://ror.org/05hnb7x64</idno>
          <idno type="Wikidata">Q138691</idno>
          <orgName>Bureau de Recherches Géologiques et Minières</orgName>
          <orgName type="acronym">BRGM</orgName>
          <desc>
            <address>
              <addrLine>Orléans (siège social) ET Directions régionales</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.brgm.fr/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-96900" status="INCOMING">
          <orgName>Centre de Développement des Géosciences Appliquées</orgName>
          <orgName type="acronym">CDGA</orgName>
          <desc>
            <address>
              <addrLine>Université Bordeaux1</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-301855" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-92972" status="VALID">
          <orgName>Université Sciences et Technologies - Bordeaux 1</orgName>
          <orgName type="acronym">UB</orgName>
          <date type="start">1971-01-01</date>
          <date type="end">2013-12-31</date>
          <desc>
            <address>
              <addrLine>351 cours de la Libération - 33405 Talence.</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.u-bordeaux1.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-301855" status="VALID">
          <orgName>Ministère de l'Education nationale, de l’Enseignement supérieur et de la Recherche</orgName>
          <orgName type="acronym">M.E.N.E.S.R.</orgName>
          <desc>
            <address>
              <addrLine>1 rue Descartes - 75231 Paris cedex 05</addrLine>
              <country key="FR"/>
            </address>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>