Catalysis without a headache: Modification of ibuprofen for the design of artificial metalloenzyme for sulfide oxidation - Archive ouverte HAL
Article Dans Une Revue Journal of Molecular Catalysis A: Chemical Année : 2016

Catalysis without a headache: Modification of ibuprofen for the design of artificial metalloenzyme for sulfide oxidation

Résumé

A new artificial oxidase has been developed for selective transformation of thioanisole. The catalytic activity of an iron inorganic complex, FeLibu, embedded in a transport protein NikA has been investigated in aqueous media. High efficiency (up to 1367 t), frequency 459 TON min(-1) and selectivity (up to 69%) make this easy to use catalytic system an asset for a sustainable chemistry. (C) 2016 Elsevier B.V. All rights reserved.

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Catalyse

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https://hal.science/hal-01323912

Soumis le : mardi 31 mai 2016-13:14:30

Dernière modification le : mardi 3 septembre 2024-11:14:08

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hal-01323912 , version 1 (31-05-2016)

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Laurianne Rondot, Elodie Girgenti, Frédéric Oddon, Caroline Marchi-Delapierre, Adeline Jorge-Robin, et al.. Catalysis without a headache: Modification of ibuprofen for the design of artificial metalloenzyme for sulfide oxidation. Journal of Molecular Catalysis A: Chemical, 2016, 416, pp.20-28. ⟨10.1016/j.molcata.2016.02.015⟩. ⟨hal-01323912⟩

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