<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-01323562</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-14T05:15:29+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Reduction of thin-film ceria on Pt(111) by supported Pd nanoparticles probed with resonant photoemission</title>
            <author role="aut">
              <persName>
                <forename type="first">J.</forename>
                <surname>Matharu</surname>
              </persName>
              <idno type="halauthorid">975101-0</idno>
              <affiliation ref="#struct-300875"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Gregory</forename>
                <surname>Cabailh</surname>
              </persName>
              <email type="md5">06e0f3c15447d2a591c44d276ede6188</email>
              <email type="domain">insp.upmc.fr</email>
              <idno type="idhal" notation="string">gregory-cabailh</idno>
              <idno type="idhal" notation="numeric">11007</idno>
              <idno type="halauthorid" notation="string">28307-11007</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-8053-2132</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=eenAtuYAAAAJ&amp;hl=en</idno>
              <idno type="IDREF">https://www.idref.fr/233127089</idno>
              <affiliation ref="#struct-440030"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">R.</forename>
                <surname>Lindsay</surname>
              </persName>
              <idno type="halauthorid">80087-0</idno>
              <affiliation ref="#struct-469410"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">C.L.</forename>
                <surname>Pang</surname>
              </persName>
              <idno type="halauthorid">1032080-0</idno>
              <affiliation ref="#struct-300875"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">D.C.</forename>
                <surname>Grinter</surname>
              </persName>
              <idno type="halauthorid">1032081-0</idno>
              <affiliation ref="#struct-300875"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">T.</forename>
                <surname>Skála</surname>
              </persName>
              <idno type="halauthorid">1032082-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">G.</forename>
                <surname>Thornton</surname>
              </persName>
              <idno type="halauthorid">276285-0</idno>
              <affiliation ref="#struct-300875"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Gregory</forename>
                <surname>Cabailh</surname>
              </persName>
              <email type="md5">06e0f3c15447d2a591c44d276ede6188</email>
              <email type="domain">insp.upmc.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2020-05-20 14:38:58</date>
              <date type="whenModified">2026-01-27 09:44:46</date>
              <date type="whenReleased">2020-05-25 11:17:22</date>
              <date type="whenProduced">2011</date>
              <date type="whenEndEmbargoed">2020-05-20</date>
              <ref type="file" target="https://hal.science/hal-01323562v1/document">
                <date notBefore="2020-05-20"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-01323562v1/file/CeO2_thinfilm.pdf" id="file-2613860-2450794">
                <date notBefore="2020-05-20"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="365900">
                <persName>
                  <forename>Gregory</forename>
                  <surname>Cabailh</surname>
                </persName>
                <email type="md5">06e0f3c15447d2a591c44d276ede6188</email>
                <email type="domain">insp.upmc.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-01323562</idno>
            <idno type="halUri">https://hal.science/hal-01323562</idno>
            <idno type="halBibtex">matharu:hal-01323562</idno>
            <idno type="halRefHtml">&lt;i&gt;Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces&lt;/i&gt;, 2011, 605 (11-12), pp.1062-1066. &lt;a target="_blank" href="https://dx.doi.org/10.1016/j.susc.2011.03.005"&gt;&amp;#x27E8;10.1016/j.susc.2011.03.005&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces, 2011, 605 (11-12), pp.1062-1066. &amp;#x27E8;10.1016/j.susc.2011.03.005&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-2613860-2450794"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="UPMC" corresp="SORBONNE-UNIVERSITE">Université Pierre et Marie Curie</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="INSP" corresp="SORBONNE-UNIVERSITE">Institut des Nanosciences de Paris</idno>
            <idno type="stamp" n="ALLINSP">Tout INSP</idno>
            <idno type="stamp" n="INSP-E9" corresp="INSP">Oxydes en basses dimensions</idno>
            <idno type="stamp" n="UPMC_POLE_2" corresp="UPMC">UPMC Pôle 2</idno>
            <idno type="stamp" n="SORBONNE-UNIVERSITE">Sorbonne Université</idno>
            <idno type="stamp" n="SU-SCIENCES" corresp="SORBONNE-UNIVERSITE">Faculté des Sciences de Sorbonne Université</idno>
            <idno type="stamp" n="SU-TI">Sorbonne Université - Texte Intégral</idno>
            <idno type="stamp" n="ALLIANCE-SU"> Alliance Sorbonne Université</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Reduction of thin-film ceria on Pt(111) by supported Pd nanoparticles probed with resonant photoemission</title>
                <author role="aut">
                  <persName>
                    <forename type="first">J.</forename>
                    <surname>Matharu</surname>
                  </persName>
                  <idno type="halauthorid">975101-0</idno>
                  <affiliation ref="#struct-300875"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Gregory</forename>
                    <surname>Cabailh</surname>
                  </persName>
                  <email type="md5">06e0f3c15447d2a591c44d276ede6188</email>
                  <email type="domain">insp.upmc.fr</email>
                  <idno type="idhal" notation="string">gregory-cabailh</idno>
                  <idno type="idhal" notation="numeric">11007</idno>
                  <idno type="halauthorid" notation="string">28307-11007</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-8053-2132</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=eenAtuYAAAAJ&amp;hl=en</idno>
                  <idno type="IDREF">https://www.idref.fr/233127089</idno>
                  <affiliation ref="#struct-440030"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">R.</forename>
                    <surname>Lindsay</surname>
                  </persName>
                  <idno type="halauthorid">80087-0</idno>
                  <affiliation ref="#struct-469410"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">C.L.</forename>
                    <surname>Pang</surname>
                  </persName>
                  <idno type="halauthorid">1032080-0</idno>
                  <affiliation ref="#struct-300875"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">D.C.</forename>
                    <surname>Grinter</surname>
                  </persName>
                  <idno type="halauthorid">1032081-0</idno>
                  <affiliation ref="#struct-300875"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">T.</forename>
                    <surname>Skála</surname>
                  </persName>
                  <idno type="halauthorid">1032082-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">G.</forename>
                    <surname>Thornton</surname>
                  </persName>
                  <idno type="halauthorid">276285-0</idno>
                  <affiliation ref="#struct-300875"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">19241</idno>
                <idno type="issn">0039-6028</idno>
                <idno type="eissn">1879-2758</idno>
                <title level="j">Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">605</biblScope>
                  <biblScope unit="issue">11-12</biblScope>
                  <biblScope unit="pp">1062-1066</biblScope>
                  <date type="datePub">2011</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1016/j.susc.2011.03.005</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">XPS</term>
                <term xml:lang="en">RESPES</term>
                <term xml:lang="en">palladium</term>
                <term xml:lang="en">resonant photoemission</term>
                <term xml:lang="en">thin film</term>
                <term xml:lang="en">Ceria</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.mate">Chemical Sciences/Material chemistry</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Local defects present in CeO 2-x films result in a mixture of Ce 3+ and Ce 4+ oxidation states. Previous studies of the Ce 3d region with XPS have shown that depositing metal nanoparticles on ceria films causes further reduction, with an increase in Ce 3+ concentration. Here, we compare the use of XPS and resonant photoemission spectroscopy (RESPES) to estimate the concentration of Ce 3+ and Ce 4+ in CeO 2-x films grown on Pt (111), and the variation of this concentration as a function of Pd deposition. Due to the nature of the electronic structure of CeO 2-x , resonant peaks are observed for the 4d-4f transitions when the photon energy matches the resonant energy; (hν=121.0 eV) for Ce 3+ and (hν=124.5 eV) for Ce 4+. This results in two discrete resonant photoemission peaks in valence band spectra. The ratio of the difference of these peaks with off-resonance scans gives an indication of the relative contribution of Ce 3+. Results from RESPES indicate reduction of CeO 2-x on deposition of Pd, confirming earlier findings from XPS studies.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="institution" xml:id="struct-300875" status="VALID">
          <idno type="IdRef">029789753</idno>
          <idno type="ROR">https://ror.org/02jx3x895</idno>
          <orgName>University College London [UCL]</orgName>
          <orgName type="acronym">UCL</orgName>
          <desc>
            <address>
              <addrLine>Gower Street, London WC1E 6BT</addrLine>
              <country key="GB"/>
            </address>
            <ref type="url">http://www.ucl.ac.uk/</ref>
          </desc>
        </org>
        <org type="researchteam" xml:id="struct-440030" status="OLD">
          <orgName>Oxydes en basses dimensions</orgName>
          <orgName type="acronym">INSP-E9</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-101592" type="direct"/>
            <relation active="#struct-93591" type="indirect"/>
            <relation name="UMR7588" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-469410" status="VALID">
          <orgName>School of Materials [Manchester]</orgName>
          <desc>
            <address>
              <addrLine>Oxford Road, Manchester, M13 9PL</addrLine>
              <country key="GB"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-121172" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-101592" status="OLD">
          <idno type="RNSR">199712634A</idno>
          <orgName>Institut des Nanosciences de Paris</orgName>
          <orgName type="acronym">INSP</orgName>
          <date type="start">1997-01-01</date>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>Université Pierre et Marie Curie Case 840 4 place Jussieu 75252 Paris Cedex 05</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insp.upmc.fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-93591" type="direct"/>
            <relation name="UMR7588" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-93591" status="OLD">
          <idno type="ROR">https://ror.org/02en5vm52</idno>
          <orgName>Université Pierre et Marie Curie - Paris 6</orgName>
          <orgName type="acronym">UPMC</orgName>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>4 place Jussieu - 75005 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.upmc.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-121172" status="VALID">
          <idno type="IdRef">224790781</idno>
          <idno type="ROR">https://ror.org/027m9bs27</idno>
          <orgName>University of Manchester [Manchester]</orgName>
          <desc>
            <address>
              <addrLine>Oxford Rd, Manchester M13 9PL</addrLine>
              <country key="GB"/>
            </address>
            <ref type="url">http://www.manchester.ac.uk/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>