Contrast-matching gone wrong? A study of polymer conformation in nanocomposites - Archive ouverte HAL
Communication Dans Un Congrès Année : 2015

Contrast-matching gone wrong? A study of polymer conformation in nanocomposites

Christelle Dupas
  • Fonction : Auteur
  • PersonId : 949232
Anne-Caroline Genix
Amélie Banc

Résumé

The structure of polymer nanocomposites has important consequences on final properties, like for instance mechanical reinforcement. While the structure of the hard filler phase is usually characterized by electron microscopy and small-angle X-ray scattering, the chain conformation can only be measured by small-angle neutron scattering (SANS). Continuous efforts over the past 15 years have produced a body of sometimes contradictory, because system-dependent, results. In virtually all studies, however, a mismatch ruining the polymer form factor at low-angles has been observed, in spite of careful contrast-matching. In this study, the conformation of polymer chains in silica-latex-nanocomposites has been studied under zero-average contrast conditions using SANS.
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Dates et versions

hal-01297465 , version 1 (04-04-2016)

Identifiants

  • HAL Id : hal-01297465 , version 1

Citer

Julian Oberdisse, Christelle Dupas, Anne-Caroline Genix, Amélie Banc. Contrast-matching gone wrong? A study of polymer conformation in nanocomposites. JCNS Workshop 2015: Neutron Scattering on Nano-Structured Soft Matter, Oct 2015, Tutzing, Germany. ⟨hal-01297465⟩
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