n a non-magnetic dielectric sphere of high-permittivity ( <20), effective magnetic response occurs as a result of the 1st Mie mode, known as the magnetic dipole resonance. This resonance produces a similar effect as split ring resonators, making it possible to use dielectric spheres as metamaterial components. In the terahertz (THz) part of the spectrum, where dielectrics with  ~100 can be found, all-dielectric metamaterials can potentially reduce absorption and provide isotropic and polarization-independent properties. In this contribution, we discuss TiO2 micro-spheres, ~1/10 of the wavelength in diameter. Such spheres are expected to support the magnetic and electric dipole resonances. To detect these resonances in a single TiO2 microsphere we use THz near-field microscopy with the sub-wavelength size aperture probe. This method allows detection of Mie resonances in single sub-wavelength spheres. Fano-type line-shape is observed in the near-field amplitude and phase spectra. The narrow line-width of the magnetic resonance and the subwavelength size of the TiO2 microspheres make them excellent candidates for realizing low-loss THz metamaterials. © (2015) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.