Easy methods for the electropolymerization of porphyrins based on the oxidation of the macrocycles - Archive ouverte HAL
Article Dans Une Revue Electrochimica Acta Année : 2011

Easy methods for the electropolymerization of porphyrins based on the oxidation of the macrocycles

Delphine Schaming
  • Fonction : Auteur
Iftikhar Ahmed
  • Fonction : Auteur
Jian Hao
  • Fonction : Auteur
Valérie Alain-Rizzo
  • Fonction : Auteur
  • PersonId : 848135
Michel Goldmann
Hualong Xu
  • Fonction : Auteur
Alain Giraudeau
  • Fonction : Auteur
Pierre Audebert
  • Fonction : Auteur
  • PersonId : 914730
Laurent Ruhlmann

Résumé

Two different methods of electropolymerization of porphyrins have been investigated and compared. They consist in the nucleophilic attack of Lewis bases onto electrogenerated dications of octaethylporphyrins. In the first method, a nucleophilic group has been directly grafted onto the macrocycle (ZnOEP-meso-bpy(+)), while in the second one, free di-nucleophilic compounds (Nu-Nu) have been used in presence of a non-substituted porphyrin (ZnOEP). The advantage of the second method is to easily modify the nature of the bridging spacer between the macrocycles. Characterizations of the polymer obtained from the second method in the case of dipyridinium-tetrazine spacer are presented. (C) 2011 Elsevier Ltd. All rights reserved.

Dates et versions

hal-01239025 , version 1 (07-12-2015)

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Citer

Delphine Schaming, Iftikhar Ahmed, Jian Hao, Valérie Alain-Rizzo, Rana Farha, et al.. Easy methods for the electropolymerization of porphyrins based on the oxidation of the macrocycles. Electrochimica Acta, 2011, 56 (28, SI), pp.10454-10463. ⟨10.1016/j.electacta.2011.02.064⟩. ⟨hal-01239025⟩
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