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Journal Articles Chemical Communications Year : 2015

Oxidative inactivation of NiFeSe hydrogenase

Abstract

We propose a resolution to the paradox that spectroscopic studies of NiFeSe hydrogenase have not revealed any major signal attributable to NiIII states formed upon reaction with O2, despite the fact that two inactive states are formed upon either aerobic or anaerobic oxidation.
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Dates and versions

hal-01211493 , version 1 (05-10-2015)

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Pierre Ceccaldi, Marta Marques, Vincent Fourmond, Inês Cardoso Pereira, Christophe Léger. Oxidative inactivation of NiFeSe hydrogenase. Chemical Communications, 2015, ⟨10.1039/C5CC05930E⟩. ⟨hal-01211493⟩

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CNRS UNIV-AMU
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