We state and prove new properties about Doeblin's ergodicity coefficient for finite Markov chains. We show that this coefficient satisfies a sub-multiplicative type inequality (analogous to the Markov-Dobrushin's ergodicity coefficient), and provide a novel but elementary proof of Doeblin's characterization of weak-ergodicity for non-homogeneous chains. Using Doeblin's coefficient, we illustrate how to approximate a homogeneous but possibly non-stationary Markov chain of duration $n$ by independent and short-lived realizations of an auxiliary chain of duration of order $\ln (n)$. This leads to approximations of occupancy distributions in homogeneous chains, which may be particularly useful when exact calculations via one-step methods or transfer matrices are impractical, and when asymptotic approximations may not be yet reliable. Our findings may find applications to pattern problems in Markovian and non-Markovian sequences that are treatable via embedding techniques.