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Article Dans Une Revue Green Chemistry Année : 2013

Reduction of aromatic and aliphatic nitro groups to anilines and amines with hypophosphites associated with Pd/C

Résumé

The reduction of aromatic and aliphatic nitro groups to anilines and amines is performed with good yield and selectivity in short reaction times. A mixture of sodium hypophosphite and phosphinic acid is used in the presence of a heterogeneous catalyst 2.5 mol% of Pd/C (5%) in a biphasic water/2-MeTHF system.

Domaines

Chimie organique
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Dates et versions

hal-01179144 , version 1 (21-07-2015)

Identifiants

  • HAL Id : hal-01179144 , version 1

Citer

Marc Baron, Estelle Métay, Marc Lemaire, Florence Popowycz. Reduction of aromatic and aliphatic nitro groups to anilines and amines with hypophosphites associated with Pd/C. Green Chemistry, 2013, 15, pp.1006-1015. ⟨hal-01179144⟩
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