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Article Dans Une Revue Journal of the American Chemical Society Année : 2013

Catalytic hydrotrifluoromethylation of unactivited alkenes

Résumé

A visible-light-mediated hydrotrifluoromethylation of unactivated alkenes that uses the Umemoto reagent as the CF3 source and MeOH as the reductant is disclosed. This effective transformation operates at room temperature in the presence of 5 mol % Ru(bpy)3Cl2; the process is characterized by its operational simplicity and functional group tolerance.

Domaines

Chimie organique
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Dates et versions

hal-01162883 , version 1 (11-06-2015)

Identifiants

  • HAL Id : hal-01162883 , version 1

Citer

Satoshi Mizuta, Stefan Verhoog, Keary M. Engle, Tanatorn Khotavivattana, Miriam O’duill, et al.. Catalytic hydrotrifluoromethylation of unactivited alkenes. Journal of the American Chemical Society, 2013, 135 (7), pp.2505-2508. ⟨hal-01162883⟩
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