First Copper(II) Phase M´0.2Mn0.8PS3• 0.25H2O and Analogous M´= CoII, NiII and ZnII Materials Obtained by Microwave Assisted Synthesis
Abstract
M'0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M' = Co(II), Ni(II), Cu(II), Zn(II)), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.
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Chemical Sciences
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First Copper(II) Phase M´0.2Mn0.8PS3• 0.25H2O_accepted.pdf (292.41 Ko)
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