Chemical activation of a mononuclear non-porphyrinic manganese complex using water as oxygen source for oxygen atom transfer reaction. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue ChemSusChem Année : 2012

Chemical activation of a mononuclear non-porphyrinic manganese complex using water as oxygen source for oxygen atom transfer reaction.

Résumé

Water, a powerful ally: A MnIII complex with an N4O-coordinating ligand and a deprotonated water molecule as sixth ligand is chemically oxidized by a CeIV one-electron oxidant. The results indicate catalytic oxygen atom transfer to alkenes, with the oxygen atom originating from a water molecule. These findings demonstrate the possibility of using water as oxygen source to perform the oxidation of organic substrates.

Domaines

Chimie organique
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Dates et versions

hal-01160192 , version 1 (04-06-2015)

Identifiants

  • HAL Id : hal-01160192 , version 1

Citer

Moulay Youness El kadiri, Sanae El ghachtouli, Régis Guillot, Laurianne Billon, Marie-France Charlot, et al.. Chemical activation of a mononuclear non-porphyrinic manganese complex using water as oxygen source for oxygen atom transfer reaction.. ChemSusChem, 2012, 5 (11), pp.2147-2150. ⟨hal-01160192⟩
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