Article Dans Une Revue European Journal of Organic Chemistry Année : 2014

Fe(TAML)Li/(diacetoxyiodo)benzene-mediated oxidation of alcohols : Evidence for mild and selective C-O and C-C oxidative cleavage in lignin model transformations.

Résumé

A novel combination of Fe(TAML)Li and (diacetoxyiodo)benzene for the oxidation of primary and secondary alcohols at 25 °C in acetone is reported. In view of the interesting ability of this system to selectively cleave specific types of C–C bonds of elaborated alcohols, the application of this novel combination to the oxidative cleavage of lignin model molecules was investigated. Considering the numerous supported versions of the oxidant as well as the mild conditions employed, the developed methodology appears to be a promising lignin depolymerization strategy.

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Dates et versions

hal-01149168 , version 1 (06-05-2015)

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  • HAL Id : hal-01149168 , version 1

Citer

Napoly François, Jean-Gérard Ludivine, Goux-Henry Catherine, M. Draye, Andrioletti Bruno. Fe(TAML)Li/(diacetoxyiodo)benzene-mediated oxidation of alcohols : Evidence for mild and selective C-O and C-C oxidative cleavage in lignin model transformations.. European Journal of Organic Chemistry, 2014, 2014 (4), pp.781-787. ⟨hal-01149168⟩
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