Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2 to cyclic carbonates - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Catalysis Communications Année : 2014

Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2 to cyclic carbonates

Bastien Chatelet
Erwann Jeanneau
Jean-Pierre Dutasta
Alexandre Martinez
Véronique Dufaud

Résumé

Various N-substituted azaphosphatranes have been prepared and successfully applied to the synthesis of styrene carbonates from CO2 and epoxides. Enhancement of the catalytic properties of the azaphosphatrane was achieved upon pre-organization of the active site through hydrogen-bonding.
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hal-01121253 , version 1 (27-02-2015)

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Bastien Chatelet, Erwann Jeanneau, Jean-Pierre Dutasta, Vincent Robert, Alexandre Martinez, et al.. Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2 to cyclic carbonates. Catalysis Communications, 2014, 52, pp.26-30. ⟨10.1016/j.catcom.2014.04.004⟩. ⟨hal-01121253⟩
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