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Article Dans Une Revue Organic Letters Année : 2011

Shorter and Modular Synthesis of Hemicryptophane-tren Derivatives

Résumé

Hemicryptophanes are host molecules with many applications as supramolecular catalysts or in ion selective recognition. A very convenient and efficient modular approach for the synthesis of hemicryptophane-tren (tren, tris(2-aminoethyl)-amine) derivatives has been developed. For instance, hemicryptophane 1 was synthesized at the gram scale in four steps from vanillyl alcohol compared to the previous seven-step procedure. The size, shape, and functionalities of the molecular cavity were also easily modified.

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Chimie organique
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Dates et versions

hal-01116906 , version 1 (15-02-2015)

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Bastien Chatelet, Elina Payet, Olivier Perraud, Pascal Dimitrov-Raytchev, Laure-Lise Chapellet, et al.. Shorter and Modular Synthesis of Hemicryptophane-tren Derivatives. Organic Letters, 2011, 13 (14), pp.3706-3709. ⟨10.1021/ol201355t⟩. ⟨hal-01116906⟩
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