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Article Dans Une Revue Applied Organometallic Chemistry Année : 2013

Synthesis of new iron-NHC complexes as catalysts for hydrosilylation reactions

Demir Serpil
  • Fonction : Auteur
Gökçe Yasemin
  • Fonction : Auteur
Nazan Kaloğlu
  • Fonction : Auteur
Ismail Ozdemir
  • Fonction : Auteur

Résumé

A series of new piano-stool iron(II) complexes comprising N-heterocyclic carbene ligands [Fe(Cp)(CO)2(NHC)]I (NHC = 1,3-disubstituted imidazolidin-2-ylidene) have been synthesized and analyzed by 1H NMR, 13C NMR, IR, elemental analysis and mass spectrometric techniques. These compounds were easily prepared from the reaction of disubstituted imidazolidin-2-ylidene with [FeI(Cp)(CO)2] in toluene at room temperature. These complexes were tested in the catalytic hydrosilylation reaction of aldehydes and ketones with phenylsilane in solvent-free conditions. After a basic hydrolysis step, the corresponding alcohols were obtained in good yields. Copyright © 2013 John Wiley & Sons, Ltd.

Domaines

Catalyse

Dates et versions

hal-01089236 , version 1 (01-12-2014)

Identifiants

Citer

Demir Serpil, Gökçe Yasemin, Nazan Kaloğlu, Jean-Baptiste Sortais, Christophe Darcel, et al.. Synthesis of new iron-NHC complexes as catalysts for hydrosilylation reactions. Applied Organometallic Chemistry, 2013, 27, pp.459-464. ⟨10.1002/aoc.3006⟩. ⟨hal-01089236⟩
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