Unprecedented Sensitization of Visible and Near-Infrared Lanthanide Luminescence by Using a Tetrathiafulvalene-Based Chromophore - Archive ouverte HAL
Article Dans Une Revue Asian Journal of Chemistry Année : 2014

Unprecedented Sensitization of Visible and Near-Infrared Lanthanide Luminescence by Using a Tetrathiafulvalene-Based Chromophore

Résumé

Based on d. functional calcns. on model systems, the electronic structure of medium and large ligated palladium clusters is discussed herein. Among all the studied clusters, the electronic structure of Pd30(CO)​26(PR3)​10, Pd69(CO)​36(PR3)​18 and Pd145(CO)​56(PR3)​30 clusters is analyzed in details. It is shown that the evolution of the band gap can be correlated to the av. Pd-​Pd bond length rather than n, the nuclearity of the cluster.

Dates et versions

hal-01088581 , version 1 (28-11-2014)

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Min Feng, Fabrice Pointillart, Boris Le guennic, Bertrand Lefeuvre, Stéphane Golhen, et al.. Unprecedented Sensitization of Visible and Near-Infrared Lanthanide Luminescence by Using a Tetrathiafulvalene-Based Chromophore. Asian Journal of Chemistry, 2014, 9 (10), pp.2814-2825. ⟨10.1002/asia.201402385⟩. ⟨hal-01088581⟩
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