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Article Dans Une Revue Polymer Testing Année : 2013

Filler effects on the thermomechanical response of stretched rubbers

Résumé

This paper deals with the calorimetric analysis of deformation processes in filled styrene-butadiene rubbers. More especially, the study focuses on the effects of the addition of carbon black fillers on the calorimetric response of "demullinized" SBR. Temperature variations are measured by infrared thermography during cyclic uniaxial tensile tests at ambient temperature. Heat sources11 The term heat source is used in this paper to mean the heat power being produced or absorbed. produced or absorbed by the material due to deformation processes are deduced from temperature fields by using the heat diffusion equation. First, the results show that no mechanical (intrinsic) dissipation is detected for weakly filled SBR, meaning that the heat produced and absorbed over one mechanical cycle is the same whatever the stretch ratio reached. Second, the mechanical dissipation in highly filled SBR is significant. The quantitative analysis carried out highlights the fact that it increases quasi-linearly with the stretch ratio. Finally, a simplified framework is proposed to discuss the identification of the heat sources, in particular the mechanical dissipation.

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hal-01073888 , version 1 (12-05-2020)

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José Ricardo Samaca Martinez, Jean-Benoit Le Cam, Xavier Balandraud, Evelyne Toussaint, Julien Caillard. Filler effects on the thermomechanical response of stretched rubbers. Polymer Testing, 2013, 32 (5), pp.835-841. ⟨10.1016/j.polymertesting.2013.04.003⟩. ⟨hal-01073888⟩
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