Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step. - Archive ouverte HAL Access content directly
Journal Articles Chemical Communications Year : 2013

Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.

Abstract

A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl](+) proceeds through proton-coupled electron transfer steps.
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Dates and versions

hal-01069157 , version 1 (28-09-2014)

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Sigolène Canaguier, Vincent Fourmond, Carlo U Perotto, Jennifer Fize, Jacques Pécaut, et al.. Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.. Chemical Communications, 2013, 49 (44), pp.5004-6. ⟨10.1039/c3cc40987b⟩. ⟨hal-01069157⟩
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