Extended and functionalized porous iron( III ) tri- or dicarboxylates with MIL-100/101 topologies
Patricia Horcajada
(1)
,
Hubert Chevreau
(1)
,
Daniela Heurtaux
(1, 2)
,
Farah Benyettou
(1)
,
Fabrice Salles
(3)
,
Thomas Devic
(1)
,
Alfonso Garcia-Marquez
(1)
,
Cihang Yu
(1)
,
Hubert Lavrard
(1)
,
Claire L. Dutson
(1)
,
Emmanuel Magnier
(1)
,
Guillaume Maurin
(3)
,
Erik Elkaim
(4)
,
Christian Serre
(1)
Patricia Horcajada
- Fonction : Auteur
- PersonId : 759930
- ORCID : 0000-0002-6544-5911
- IdRef : 175644276
Fabrice Salles
- Fonction : Auteur
- PersonId : 739071
- IdHAL : fabrice-salles
- ORCID : 0000-0001-8069-533X
- IdRef : 077044878
Emmanuel Magnier
- Fonction : Auteur
- PersonId : 178854
- IdHAL : emmanuel-magnier
- ORCID : 0000-0003-3392-3971
- IdRef : 14983148X
Guillaume Maurin
- Fonction : Auteur
- PersonId : 169721
- IdHAL : guillaume-maurin
- ORCID : 0000-0002-2096-0450
- IdRef : 068982127
Christian Serre
- Fonction : Auteur
- PersonId : 741918
- IdHAL : christian-serre
- ORCID : 0000-0003-3040-2564
- IdRef : 060906294
Résumé
A series of nanometric isoreticular and/or functionalized analogues of the mesoporous environmentally-friendly iron( III ) polycarboxylates MIL-100/101 have been successfully synthesized. Their exceptional pore size, of up to 68 Å, together with their relatively good stability in solvents, makes them promising candidates for heterogeneous catalysis or inclusion of large molecules, among others.