<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-01020208</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-13T20:01:30+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Dye photosensitized cationic ring-opening polymerization: Search for new dye skeletons</title>
            <author role="aut">
              <persName>
                <forename type="first">Jacques</forename>
                <surname>Lalevée</surname>
              </persName>
              <email type="md5">c9b27df8cef13f20234a9b1db8cb2fa3</email>
              <email type="domain">uha.fr</email>
              <idno type="idhal" notation="numeric">769075</idno>
              <idno type="halauthorid" notation="string">728379-769075</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-9297-0335</idno>
              <idno type="IDREF">https://www.idref.fr/076038025</idno>
              <idno type="VIAF">https://viaf.org/viaf/306128532</idno>
              <idno type="ISNI">http://isni.org/isni/0000000400291549</idno>
              <affiliation ref="#struct-505910"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Frédéric</forename>
                <surname>Dumur</surname>
              </persName>
              <email type="md5">0297854ef7d76d331797e5ab794770ef</email>
              <email type="domain">univ-amu.fr</email>
              <idno type="idhal" notation="numeric">757987</idno>
              <idno type="halauthorid" notation="string">205903-757987</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-4872-094X</idno>
              <idno type="IDREF">https://www.idref.fr/070474990</idno>
              <idno type="VIAF">https://viaf.org/viaf/193825864</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/N-1856-2013</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=Uii-QDQAAAAJ</idno>
              <affiliation ref="#struct-258556"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Mohamad Ali</forename>
                <surname>Tehfe</surname>
              </persName>
              <idno type="halauthorid">633097-0</idno>
              <affiliation ref="#struct-190758"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Abbas</forename>
                <surname>Zein-Fakih</surname>
              </persName>
              <idno type="halauthorid">845490-0</idno>
              <affiliation ref="#struct-505910"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Didier</forename>
                <surname>Gigmes</surname>
              </persName>
              <email type="md5">b9a482188c4f84417c5298a4e23b00e1</email>
              <email type="domain">univ-amu.fr</email>
              <idno type="idhal" notation="numeric">956680</idno>
              <idno type="halauthorid" notation="string">829546-956680</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-8833-8393</idno>
              <idno type="IDREF">https://www.idref.fr/069850518</idno>
              <idno type="VIAF">https://viaf.org/viaf/220100048</idno>
              <affiliation ref="#struct-258556"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Fabrice</forename>
                <surname>Morlet-Savary</surname>
              </persName>
              <idno type="halauthorid">118192-0</idno>
              <affiliation ref="#struct-505910"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Bernadette</forename>
                <surname>Graff</surname>
              </persName>
              <idno type="halauthorid">209037-0</idno>
              <affiliation ref="#struct-505910"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Jean-Pierre</forename>
                <surname>Fouassier</surname>
              </persName>
              <idno type="halauthorid">117183-0</idno>
              <affiliation ref="#struct-505910"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Frederic</forename>
                <surname>Dumur</surname>
              </persName>
              <email type="md5">0297854ef7d76d331797e5ab794770ef</email>
              <email type="domain">univ-amu.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2014-07-07 21:55:51</date>
              <date type="whenWritten">2012-08-30</date>
              <date type="whenModified">2025-04-10 09:41:18</date>
              <date type="whenReleased">2014-07-07 21:55:51</date>
              <date type="whenProduced">2012-09-07</date>
              <ref type="externalLink" target="https://api.istex.fr/ark:/67375/6H6-QSG58L3G-L/fulltext.pdf?sid=hal"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="194828">
                <persName>
                  <forename>Frederic</forename>
                  <surname>Dumur</surname>
                </persName>
                <email type="md5">0297854ef7d76d331797e5ab794770ef</email>
                <email type="domain">univ-amu.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-01020208</idno>
            <idno type="halUri">https://hal.science/hal-01020208</idno>
            <idno type="halBibtex">lalevee:hal-01020208</idno>
            <idno type="halRefHtml">&lt;i&gt;Polymer&lt;/i&gt;, 2012, 53, pp.4947-4954. &lt;a target="_blank" href="https://dx.doi.org/10.1016/j.polymer.2012.08.067"&gt;&amp;#x27E8;10.1016/j.polymer.2012.08.067&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Polymer, 2012, 53, pp.4947-4954. &amp;#x27E8;10.1016/j.polymer.2012.08.067&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-AMU">Aix Marseille Université</idno>
            <idno type="stamp" n="UNIV-STRASBG">Université de Strasbourg</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="SITE-ALSACE">Archive ouverte du site Alsace</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
            <idno type="stamp" n="LABORATOIRES-UHA" corresp="UHA">Laboratoires de l'Université de Haute-Alsace (UHA)</idno>
            <idno type="stamp" n="UHA">Université de Haute-Alsace (UHA)</idno>
            <idno type="stamp" n="IS2M">IS2M - Institut de Science des Matériaux de Mulhouse</idno>
            <idno type="stamp" n="LPIM">LPIM - Laboratoire de Photochimie et d'ingénierie macromoléculaires</idno>
            <idno type="stamp" n="ICR-AMU">Institut de Chimie Radicalaire</idno>
            <idno type="stamp" n="ORIGINES">Institut Origines, des planètes à la vie</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Dye photosensitized cationic ring-opening polymerization: Search for new dye skeletons</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Jacques</forename>
                    <surname>Lalevée</surname>
                  </persName>
                  <email type="md5">c9b27df8cef13f20234a9b1db8cb2fa3</email>
                  <email type="domain">uha.fr</email>
                  <idno type="idhal" notation="numeric">769075</idno>
                  <idno type="halauthorid" notation="string">728379-769075</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-9297-0335</idno>
                  <idno type="IDREF">https://www.idref.fr/076038025</idno>
                  <idno type="VIAF">https://viaf.org/viaf/306128532</idno>
                  <idno type="ISNI">http://isni.org/isni/0000000400291549</idno>
                  <affiliation ref="#struct-505910"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Frédéric</forename>
                    <surname>Dumur</surname>
                  </persName>
                  <email type="md5">0297854ef7d76d331797e5ab794770ef</email>
                  <email type="domain">univ-amu.fr</email>
                  <idno type="idhal" notation="numeric">757987</idno>
                  <idno type="halauthorid" notation="string">205903-757987</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-4872-094X</idno>
                  <idno type="IDREF">https://www.idref.fr/070474990</idno>
                  <idno type="VIAF">https://viaf.org/viaf/193825864</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/N-1856-2013</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=Uii-QDQAAAAJ</idno>
                  <affiliation ref="#struct-258556"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Mohamad Ali</forename>
                    <surname>Tehfe</surname>
                  </persName>
                  <idno type="halauthorid">633097-0</idno>
                  <affiliation ref="#struct-190758"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Abbas</forename>
                    <surname>Zein-Fakih</surname>
                  </persName>
                  <idno type="halauthorid">845490-0</idno>
                  <affiliation ref="#struct-505910"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Didier</forename>
                    <surname>Gigmes</surname>
                  </persName>
                  <email type="md5">b9a482188c4f84417c5298a4e23b00e1</email>
                  <email type="domain">univ-amu.fr</email>
                  <idno type="idhal" notation="numeric">956680</idno>
                  <idno type="halauthorid" notation="string">829546-956680</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-8833-8393</idno>
                  <idno type="IDREF">https://www.idref.fr/069850518</idno>
                  <idno type="VIAF">https://viaf.org/viaf/220100048</idno>
                  <affiliation ref="#struct-258556"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Fabrice</forename>
                    <surname>Morlet-Savary</surname>
                  </persName>
                  <idno type="halauthorid">118192-0</idno>
                  <affiliation ref="#struct-505910"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Bernadette</forename>
                    <surname>Graff</surname>
                  </persName>
                  <idno type="halauthorid">209037-0</idno>
                  <affiliation ref="#struct-505910"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Jean-Pierre</forename>
                    <surname>Fouassier</surname>
                  </persName>
                  <idno type="halauthorid">117183-0</idno>
                  <affiliation ref="#struct-505910"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">16533</idno>
                <idno type="issn">0032-3861</idno>
                <title level="j">Polymer</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">53</biblScope>
                  <biblScope unit="pp">4947-4954</biblScope>
                  <date type="datePub">2012-09-07</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1016/j.polymer.2012.08.067</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Dyes</term>
                <term xml:lang="en">Photoinitiators</term>
                <term xml:lang="en">Halogen lamp</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.mate">Chemical Sciences/Material chemistry</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>New dyes (based on diamine, oligophenylenevinylene, salphen ligands and polyazine skeletons) are checked here for the formation of free radicals under very soft irradiation conditions (halogen lamp, blue or green LED bulbs and laser diode at 457 nm) under air. Three component systems involving a combination of diamine (or oligophenylenevinylene) dye/diphenyl iodonium salt/silane (or N-vinylcarbazole NVK) are used. Excellent ring-opening polymerization ROP profiles are obtained. A comparison of the ability of these dyes vs. Eosin-Y (used as a well known reference dye) is also provided. The chemical mechanisms are investigated in detail by ESR and luminescence experiments. Upon a visible light exposure, these systems generate aryl, silyl or aN radicals that can be easily oxidized to promote the ringopening polymerization of epoxy monomers. In every case, the silyliums (R3Siþ) or the N-vinylcarbazole derived cations (NVKþ) are the polymerization initiating structures.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-505910" status="VALID">
          <idno type="RNSR">201320577P</idno>
          <idno type="ROR">https://ror.org/012wxdw12</idno>
          <orgName>Institut de Science des Matériaux de Mulhouse</orgName>
          <orgName type="acronym">IS2M</orgName>
          <desc>
            <address>
              <addrLine>15 rue Jean Starcky BP 2488 68057 MULHOUSE CEDEX 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.is2m.uha.fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-237692" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR7361" active="#struct-441569" type="direct"/>
            <relation active="#struct-529627" type="direct"/>
            <relation name="FR3627" active="#struct-199013" type="indirect"/>
            <relation active="#struct-303623" type="indirect"/>
            <relation name="FR3627" active="#struct-441569" type="direct"/>
            <relation active="#struct-529628" type="direct"/>
            <relation name="FR3678" active="#struct-199013" type="indirect"/>
            <relation active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-258556" status="VALID">
          <idno type="ISNI">0000 0004 4902 8637</idno>
          <idno type="RNSR">201220354B</idno>
          <idno type="ROR">https://ror.org/000d5zy28</idno>
          <orgName>Institut de Chimie Radicalaire</orgName>
          <orgName type="acronym">ICR</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>Avenue Escadrille Normandie-Niemen Service D42 13397 Marseille cedex 20</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://icr-amu.cnrs.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UMR7273" active="#struct-198056" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR7273" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-190758" status="OLD">
          <orgName>Laboratoire de Photochimie et d'Ingénierie Macromoléculaires</orgName>
          <orgName type="acronym">LPIM</orgName>
          <date type="end">2019-12-31</date>
          <desc>
            <address>
              <addrLine>Maison du Technopôle 34 rue Marc Seguin MULHOUSE - FRANCE</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.lpim.uha.fr</ref>
          </desc>
          <listRelation>
            <relation name="EA4567" active="#struct-237692" type="direct"/>
            <relation active="#struct-529627" type="direct"/>
            <relation name="FR3627" active="#struct-199013" type="indirect"/>
            <relation active="#struct-237692" type="direct"/>
            <relation active="#struct-303623" type="indirect"/>
            <relation active="#struct-341038" type="indirect"/>
            <relation name="FR3627" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-237692" status="VALID">
          <idno type="IdRef">026403250</idno>
          <idno type="ISNI">0000000404735039</idno>
          <idno type="ROR">https://ror.org/04k8k6n84</idno>
          <orgName>Université de Haute-Alsace (UHA) Mulhouse - Colmar</orgName>
          <orgName type="acronym">Université de Haute-Alsace (UHA)</orgName>
          <desc>
            <address>
              <addrLine>2, rue des Frères Lumière F-68093 Mulhouse Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.uha.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="regrouplaboratory" xml:id="struct-529627" status="VALID">
          <idno type="RNSR">201420878M</idno>
          <orgName>Matériaux et Nanosciences Grand-Est</orgName>
          <orgName type="acronym">MNGE</orgName>
          <date type="start">2014-01-01</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation name="FR3627" active="#struct-199013" type="direct"/>
            <relation active="#struct-237692" type="direct"/>
            <relation active="#struct-303623" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="FR3627" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-199013" status="VALID">
          <idno type="IdRef">131056549</idno>
          <idno type="ROR">https://ror.org/00pg6eq24</idno>
          <orgName>Université de Strasbourg</orgName>
          <orgName type="acronym">UNISTRA</orgName>
          <desc>
            <address>
              <addrLine>4 rue Blaise Pascal - CS 90032 - 67081 Strasbourg cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.unistra.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-303623" status="VALID">
          <idno type="IdRef">026388278</idno>
          <idno type="ROR">https://ror.org/02vjkv261</idno>
          <orgName>Institut National de la Santé et de la Recherche Médicale</orgName>
          <orgName type="acronym">INSERM</orgName>
          <desc>
            <address>
              <addrLine>101, rue de Tolbiac, 75013 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.inserm.fr</ref>
          </desc>
        </org>
        <org type="regrouplaboratory" xml:id="struct-529628" status="VALID">
          <orgName>Réseau nanophotonique et optique</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation name="FR3678" active="#struct-199013" type="direct"/>
            <relation active="#struct-237692" type="direct"/>
            <relation active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-198056" status="VALID">
          <idno type="IdRef">15863621X</idno>
          <idno type="ISNI">0000 0001 2176 4817</idno>
          <idno type="ROR">https://ror.org/035xkbk20</idno>
          <orgName>Aix Marseille Université</orgName>
          <orgName type="acronym">AMU</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>Aix-Marseille UniversitéJardins du Pharo58 Boulevard Charles Livon13284 Marseille cedex 7</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-amu.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>