Nanoparticles of molecule-based conductors - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue New Journal of Chemistry Année : 2013

Nanoparticles of molecule-based conductors

Résumé

State of the art molecule-based conductors that have been isolated as nanoparticles are reviewed. Research efforts in this field is justified by their insolubility and low vapour pressure, making their integration into electronic devices difficult. Their availability as nanoparticles would allow researchers to study their properties at the nanoscale and as stable dispersions, offering new opportunities for processing. Molecular conductors and superconductors that have been isolated as nanoparticles are: TTF[middle dot]TCNQ, TTF[Ni(dmit)2]2, TTFCl0.77 and TTFBr0.59, (BEDT-TTF)Cl0.66 and (BEDT-TTF)2Br, (TMTSF)2ClO4 and (TMTSF)2PF6. Nanoparticle formation and shape depend on the stabilizing agent used for controlling the growth: ionic liquids, long-chain ammonium salts or neutral liquid polymers. The conductivities of the nanoparticle powders are reported.
Fichier non déposé

Dates et versions

hal-00994341 , version 1 (21-05-2014)

Identifiants

Citer

Dominique de Caro, Lydie Valade, C. Faulmann, Kane Jacob, D. van Dorsselaer, et al.. Nanoparticles of molecule-based conductors. New Journal of Chemistry, 2013, 37 (11), pp.3331-3336. ⟨10.1039/c3nj00555k⟩. ⟨hal-00994341⟩
35 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More