First efficient synthesis of fluorinated glycidic esters from ketones. - Archive ouverte HAL
Article Dans Une Revue Organic Letters Année : 2010

First efficient synthesis of fluorinated glycidic esters from ketones.

Résumé

Treatment of various ketones with ethyl dibromofluoroacetate in the presence of diethylzinc and dimethylaminoethanol or triphenylphosphine provides rapid access to corresponding fluorinated glycidic esters. Simplified workup allowed first characterization of these compounds.

Domaines

Chimie organique
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Dates et versions

hal-00991931 , version 1 (16-05-2014)

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Gérald Lemonnier, Ludivine Zoute, Jean-Charles Quirion, Philippe Jubault. First efficient synthesis of fluorinated glycidic esters from ketones.. Organic Letters, 2010, 12 (4), pp.844-846. ⟨10.1021/ol902903v⟩. ⟨hal-00991931⟩
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