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Article Dans Une Revue New Journal of Chemistry Année : 2014

Fast and continuous processing of a new submicronic lanthanide-based metal-organic framework

Résumé

Processing strategies for the synthesis of hybrid materials stand as relevant ways to modulate the particle size and morphology. We present herein the use of a continuous high temperature-high pressure (HT-HP) process for the synthesis of a new cerium based metal-organic framework (MOF). The HT-HP harsh thermodynamic synthesis conditions lead to MOF nanostructures exhibiting the same phase as for microparticles obtained under conventional batch solvothermal conditions but in exceptional much shorter residence times, opening avenues towards production scaling-up. The HT-HP process also tailors down the size of the particles, which still presents a major issue for most MOF applications.

Domaines

Matériaux
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Dates et versions

hal-00974019 , version 1 (04-04-2014)

Identifiants

Citer

Loïc d'Arras, Capucine Sassoye, Laurence Rozes, Clément Sanchez, Jérôme Marrot, et al.. Fast and continuous processing of a new submicronic lanthanide-based metal-organic framework. New Journal of Chemistry, 2014, 38 (4), pp.1477-1483. ⟨10.1039/C3NJ01371E⟩. ⟨hal-00974019⟩
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