<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-00972058</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-17T21:55:03+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Recent results in synthetic glycochemistry with iron salts at Orsay-Gif</title>
            <author role="aut">
              <persName>
                <forename type="first">J.M.</forename>
                <surname>Beau</surname>
              </persName>
              <idno type="halauthorid">336075-0</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Yann</forename>
                <surname>Bourdreux</surname>
              </persName>
              <email type="md5">2f02f49501b67d60fa33031286b19eb4</email>
              <email type="domain">u-psud.fr</email>
              <idno type="idhal" notation="string">yannbourdreux</idno>
              <idno type="idhal" notation="numeric">756792</idno>
              <idno type="halauthorid" notation="string">2547600-756792</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-6653-7685</idno>
              <idno type="IDREF">https://www.idref.fr/099248190</idno>
              <idno type="VIAF">https://viaf.org/viaf/191794813</idno>
              <idno type="ISNI">http://isni.org/isni/0000000356988751</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">F.-D.</forename>
                <surname>Boyer</surname>
              </persName>
              <idno type="halauthorid">805591-0</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">S.</forename>
                <surname>Norsikian</surname>
              </persName>
              <email type="md5">227f3dfd3b2d565e11a74658dec2ca05</email>
              <email type="domain">cnrs.fr</email>
              <idno type="idhal" notation="string">stephanie-norsikian</idno>
              <idno type="idhal" notation="numeric">740004</idno>
              <idno type="halauthorid" notation="string">10379-740004</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-2706-4007</idno>
              <idno type="IDREF">https://www.idref.fr/155013297</idno>
              <idno type="VIAF">https://viaf.org/viaf/218578986</idno>
              <idno type="ISNI">http://isni.org/isni/000000038671070X</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">D.</forename>
                <surname>Urban</surname>
              </persName>
              <email type="md5">900a520fc0d465f0352b79f8307198ab</email>
              <email type="domain">universite-paris-saclay.fr</email>
              <idno type="idhal" notation="string">dominique-urban</idno>
              <idno type="idhal" notation="numeric">1149475</idno>
              <idno type="halauthorid" notation="string">824542-1149475</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-7943-5386</idno>
              <idno type="IDREF">https://www.idref.fr/150093918</idno>
              <idno type="VIAF">https://viaf.org/viaf/210333858</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Gilles</forename>
                <surname>Doisneau</surname>
              </persName>
              <email type="md5">77dbc91e32d46a0be17e499071aac209</email>
              <email type="domain">universite-paris-saclay.fr</email>
              <idno type="idhal" notation="numeric">770956</idno>
              <idno type="halauthorid" notation="string">809281-770956</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-4195-1243</idno>
              <idno type="IDREF">https://www.idref.fr/138532613</idno>
              <idno type="ISNI">http://isni.org/isni/0000000358955494</idno>
              <idno type="VIAF">https://viaf.org/viaf/215273205</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">B.</forename>
                <surname>Vauzeilles</surname>
              </persName>
              <idno type="halauthorid">126910-0</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">A.</forename>
                <surname>Gouasmat</surname>
              </persName>
              <idno type="halauthorid">824543-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Aurélie</forename>
                <surname>Lemétais</surname>
              </persName>
              <idno type="halauthorid">782255-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Aurélie</forename>
                <surname>Mathieu</surname>
              </persName>
              <idno type="halauthorid">340755-0</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Jean-François</forename>
                <surname>Soule</surname>
              </persName>
              <email type="md5">05a790ed903e9d3b0d9e830d18a5edad</email>
              <email type="domain">chimieparistech.psl.eu</email>
              <idno type="idhal" notation="string">jean-francois-soule</idno>
              <idno type="idhal" notation="numeric">11029</idno>
              <idno type="halauthorid" notation="string">824544-11029</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-6593-1995</idno>
              <idno type="IDREF">https://www.idref.fr/155013238</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Arnaud</forename>
                <surname>Stevenin</surname>
              </persName>
              <idno type="halauthorid">663277-0</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Amandine</forename>
                <surname>Xolin</surname>
              </persName>
              <idno type="halauthorid">824545-0</idno>
              <affiliation ref="#struct-440"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Jocelyne</forename>
                <surname>Brunet</surname>
              </persName>
              <email type="md5">5e5bf5d917b4e2d903ddb1e539f7e615</email>
              <email type="domain">icsn.cnrs-gif.fr.invalid</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2014-04-03 14:57:54</date>
              <date type="whenWritten">2014</date>
              <date type="whenModified">2026-02-09 17:17:31</date>
              <date type="whenReleased">2014-04-03 14:57:54</date>
              <date type="whenProduced">2014</date>
              <ref type="externalLink" target="https://api.istex.fr/ark:/67375/P0J-WHH7FW1R-L/fulltext.pdf?sid=hal"/>
              <fs>
                <f name="inra_publicVise_local" notation="string" n="SC">
                  <string>inra_publicVise_local_SC</string>
                </f>
              </fs>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="103776">
                <persName>
                  <forename>Jocelyne</forename>
                  <surname>Brunet</surname>
                </persName>
                <email type="md5">5e5bf5d917b4e2d903ddb1e539f7e615</email>
                <email type="domain">icsn.cnrs-gif.fr.invalid</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-00972058</idno>
            <idno type="halUri">https://hal.science/hal-00972058</idno>
            <idno type="halBibtex">beau:hal-00972058</idno>
            <idno type="halRefHtml">&lt;i&gt;Carbohydrate Chemistry&lt;/i&gt;, 40, &lt;a target="_blank" href="http://dx.doi.org/10.1039/9781849739986-00118"&gt;RSC&lt;/a&gt;, pp.118-139, 2014, Volume 40, Chapitre 7, 978-1-84973-965-8. &lt;a target="_blank" href="https://dx.doi.org/10.1039/9781849739986-00118"&gt;&amp;#x27E8;10.1039/9781849739986-00118&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Carbohydrate Chemistry, 40, RSC, pp.118-139, 2014, Volume 40, Chapitre 7, 978-1-84973-965-8. &amp;#x27E8;10.1039/9781849739986-00118&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="ICSN">Collection des Publications de l'Institut de Chimie des Substances Naturelles, UPR2301, Gif sur Yvette</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="UNIV-PARIS-SACLAY">Université Paris-Saclay</idno>
            <idno type="stamp" n="UNIV-PSUD-SACLAY" corresp="UNIV-PARIS-SACLAY">Université Paris Sud pour Paris Saclay</idno>
            <idno type="stamp" n="GS-HEALTH-DRUG-SCIENCES">Graduate School Health and Drug Sciences</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
            <idno type="stamp" n="ICMMO">Institut de chimie moléculaire et des matériaux d'Orsay</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Recent results in synthetic glycochemistry with iron salts at Orsay-Gif</title>
                <author role="aut">
                  <persName>
                    <forename type="first">J.M.</forename>
                    <surname>Beau</surname>
                  </persName>
                  <idno type="halauthorid">336075-0</idno>
                  <affiliation ref="#struct-440"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Yann</forename>
                    <surname>Bourdreux</surname>
                  </persName>
                  <email type="md5">2f02f49501b67d60fa33031286b19eb4</email>
                  <email type="domain">u-psud.fr</email>
                  <idno type="idhal" notation="string">yannbourdreux</idno>
                  <idno type="idhal" notation="numeric">756792</idno>
                  <idno type="halauthorid" notation="string">2547600-756792</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-6653-7685</idno>
                  <idno type="IDREF">https://www.idref.fr/099248190</idno>
                  <idno type="VIAF">https://viaf.org/viaf/191794813</idno>
                  <idno type="ISNI">http://isni.org/isni/0000000356988751</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">F.-D.</forename>
                    <surname>Boyer</surname>
                  </persName>
                  <idno type="halauthorid">805591-0</idno>
                  <affiliation ref="#struct-440"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">S.</forename>
                    <surname>Norsikian</surname>
                  </persName>
                  <email type="md5">227f3dfd3b2d565e11a74658dec2ca05</email>
                  <email type="domain">cnrs.fr</email>
                  <idno type="idhal" notation="string">stephanie-norsikian</idno>
                  <idno type="idhal" notation="numeric">740004</idno>
                  <idno type="halauthorid" notation="string">10379-740004</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-2706-4007</idno>
                  <idno type="IDREF">https://www.idref.fr/155013297</idno>
                  <idno type="VIAF">https://viaf.org/viaf/218578986</idno>
                  <idno type="ISNI">http://isni.org/isni/000000038671070X</idno>
                  <affiliation ref="#struct-440"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">D.</forename>
                    <surname>Urban</surname>
                  </persName>
                  <email type="md5">900a520fc0d465f0352b79f8307198ab</email>
                  <email type="domain">universite-paris-saclay.fr</email>
                  <idno type="idhal" notation="string">dominique-urban</idno>
                  <idno type="idhal" notation="numeric">1149475</idno>
                  <idno type="halauthorid" notation="string">824542-1149475</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-7943-5386</idno>
                  <idno type="IDREF">https://www.idref.fr/150093918</idno>
                  <idno type="VIAF">https://viaf.org/viaf/210333858</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Gilles</forename>
                    <surname>Doisneau</surname>
                  </persName>
                  <email type="md5">77dbc91e32d46a0be17e499071aac209</email>
                  <email type="domain">universite-paris-saclay.fr</email>
                  <idno type="idhal" notation="numeric">770956</idno>
                  <idno type="halauthorid" notation="string">809281-770956</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-4195-1243</idno>
                  <idno type="IDREF">https://www.idref.fr/138532613</idno>
                  <idno type="ISNI">http://isni.org/isni/0000000358955494</idno>
                  <idno type="VIAF">https://viaf.org/viaf/215273205</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">B.</forename>
                    <surname>Vauzeilles</surname>
                  </persName>
                  <idno type="halauthorid">126910-0</idno>
                  <affiliation ref="#struct-440"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">A.</forename>
                    <surname>Gouasmat</surname>
                  </persName>
                  <idno type="halauthorid">824543-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Aurélie</forename>
                    <surname>Lemétais</surname>
                  </persName>
                  <idno type="halauthorid">782255-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Aurélie</forename>
                    <surname>Mathieu</surname>
                  </persName>
                  <idno type="halauthorid">340755-0</idno>
                  <affiliation ref="#struct-440"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Jean-François</forename>
                    <surname>Soule</surname>
                  </persName>
                  <email type="md5">05a790ed903e9d3b0d9e830d18a5edad</email>
                  <email type="domain">chimieparistech.psl.eu</email>
                  <idno type="idhal" notation="string">jean-francois-soule</idno>
                  <idno type="idhal" notation="numeric">11029</idno>
                  <idno type="halauthorid" notation="string">824544-11029</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-6593-1995</idno>
                  <idno type="IDREF">https://www.idref.fr/155013238</idno>
                  <affiliation ref="#struct-440"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Arnaud</forename>
                    <surname>Stevenin</surname>
                  </persName>
                  <idno type="halauthorid">663277-0</idno>
                  <affiliation ref="#struct-440"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Amandine</forename>
                    <surname>Xolin</surname>
                  </persName>
                  <idno type="halauthorid">824545-0</idno>
                  <affiliation ref="#struct-440"/>
                </author>
              </analytic>
              <monogr>
                <idno type="isbn">978-1-84973-965-8</idno>
                <idno type="localRef">2014037</idno>
                <title level="m">Carbohydrate Chemistry</title>
                <imprint>
                  <publisher>RSC</publisher>
                  <biblScope unit="serie">Volume 40, Chapitre 7</biblScope>
                  <biblScope unit="volume">40</biblScope>
                  <biblScope unit="pp">118-139</biblScope>
                  <date type="datePub">2014</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1039/9781849739986-00118</idno>
              <idno type="prodinra">294645</idno>
              <idno type="wos">000387269500009</idno>
              <ref target="http://dx.doi.org/10.1039/9781849739986-00118" type="seeAlso"/>
              <ref type="publisher">http://dx.doi.org/10.1039/9781849739986-00118</ref>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="chim.orga">Chemical Sciences/Organic chemistry</classCode>
              <classCode scheme="halTypology" n="COUV">Book sections</classCode>
              <classCode scheme="halOldTypology" n="COUV">Book sections</classCode>
              <classCode scheme="halTreeTypology" n="COUV">Book sections</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>This review particularly emphasizes synthetic applications resulting from cascade or one-pot transformations and a glycosylation reaction promoted by ferric salts. These easy to handle, cheap and environment-friendly salts have been examined for their ability to induce, as a Lewis acid, fast carbohydrate-based modifications in our laboratories at Orsay and Gif sur Yvette. A short synthetic route to the dihydropyran framework of anti-influenza constructs is reported by coupling the Petasis three-component condensation to an iron(iii)-promoted one-pot cascade of deprotection – C–C double bond isomerization – cyclization - oxazoline formation. We also show that iron(iii) chloride hexahydrate is most appropriate to catalyze a one-pot regioselective protection of mono- and disaccharides. This iron(iii) catalysis renders multi-step routes, such as chemical oligosaccharide syntheses, faster. In the last section, we report a catalytic glycosylation method particularly simple and straightforward leading to the important β-d-GlcNAc motif, in which the more electrophilic iron(iii) triflate activates the readily available peracetate of N-acetyl-β-d-glucosamine. This glycosylation does not necessarily require the formation of the mandatory oxazolinium intermediate.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-440" status="OLD">
          <idno type="ISNI">0000000122863155</idno>
          <idno type="RNSR">200617587V</idno>
          <idno type="ROR">https://ror.org/02st4q439</idno>
          <orgName>Institut de Chimie des Substances Naturelles</orgName>
          <orgName type="acronym">ICSN</orgName>
          <date type="start">1959-01-01</date>
          <date type="end">2019-12-31</date>
          <desc>
            <address>
              <addrLine>Avenue de la terrasse 91198 Gif-sur-Yvette cedex</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UPR2301" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>