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Article Dans Une Revue Journal of Physical Chemistry A Année : 2013

Experimental Observation and Quantum Chemical Characterization of the S1 ← S0 Transition of Protonated Naphthalene-Argon Clusters

Résumé

We report on the photodissociation spectrum of protonated naphthalene+−argon complexes (NpH+−Ar) recorded by excitation into the first excited singlet electronic state. Unlike previous electronic spectra of the free molecule (NpH+), both the α and the β isomer could be observed for the Ar adducts. Detailed information on the S0 and S1 state of both isomers is provided by quantum chemical calculations. An assignment of observed vibrational bands is proposed based on Franck−Condon simulations.
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hal-00965901 , version 1 (25-03-2014)

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Alexander Patzer, Markus Schütz, Christophe Jouvet, Otto Dopfer. Experimental Observation and Quantum Chemical Characterization of the S1 ← S0 Transition of Protonated Naphthalene-Argon Clusters. Journal of Physical Chemistry A, 2013, 117, pp.9785−9793. ⟨10.1021/jp312581v⟩. ⟨hal-00965901⟩

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