Enthalpy relaxation phenomena of epoxy adhesive in operational configuration: Thermal, mechanical and dielectric analyses
Résumé
Thermal cycling in space environment can cause physical aging of polymers used in structural adhesive bonded joint. Later, they can initiate failure. A methodology to follow physical aging effects on their thermal, mechanical and dielectric properties is applied to a commercial epoxy adhesive. The analytic description, using Tool, Narayanaswamy and Moynihan model gives a good description of the enthalpy relaxation. It is completed by a phenomenological analysis of the evolution of the adhesive thermal transitions, mechanical properties and mo- lecularmobility. Testedsamples with bondedassembly are representative ofin servicecon fi gurations. The in fl u- ence of physical aging on the adhesive and the associated bonded assemblies is analyzed.
Origine : Fichiers produits par l'(les) auteur(s)
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