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Article Dans Une Revue Transition Metal Chemistry Année : 2013

Pseudo-capsular behaviour of two trans-coordinated calixarenyl phosphines

Résumé

The square-planar complex trans-[PtCl2L2] (L = 5-diphenylphosphinyl-25,26,27,28-tetrabenzyloxy-calix[4]arene) was prepared in two steps from [PtCl2(cod)] (cod = 1,5-cyclooctadiene) and the corresponding phosphine. In the solid state, the calixarene moieties adopt a typical pinched cone conformation; they are both turned towards the Cl-Pt-Cl rod, thereby forming a capsule that hosts the platinum centre.

Dates et versions

hal-00939244 , version 1 (30-01-2014)

Identifiants

Citer

Laure Monnereau, David Semeril, Dominique Matt, Loïc Toupet. Pseudo-capsular behaviour of two trans-coordinated calixarenyl phosphines. Transition Metal Chemistry, 2013, 38 (8), pp.821-825. ⟨10.1007/s11243-013-9754-0⟩. ⟨hal-00939244⟩
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