Rolling contact fatigue has become a surface initiated problem. This phenomenon is due to the initiation and propagation of cracks from the surface to the volume of mechanical pieces. A great amount of research has been done since the 1970s to understand its origin, but many aspects remain unclear. Many authors found that the lubricant composition and especially certain additives can either improve or reduce fatigue life, depending on the operating conditions. It is now admitted that additives form a tribofilm in the rubbing track, especially under pure sliding conditions, but no direct relation to rolling contact fatigue has been drawn to this moment. The knowledge of the reaction pathways of lubricant additives under various sliding conditions as well as the tribofilm properties and morphology has become an important issue. In this work, the mini traction machine has been used to study friction under different sliding conditions of a pure mineral base oil and a formulated oil containing five selected additives. The results suggest that friction is likely to mimic tribofilm formation. The slide-to-roll ratio influences the rate of direct asperity contacts and hence tribofilm growth.