Local control of non-adiabatic dissociation dynamics - Archive ouverte HAL
Article Dans Une Revue The Journal of Chemical Physics Année : 2011

Local control of non-adiabatic dissociation dynamics

Résumé

We present a theoretical approach which consists of applying the strategy of local control to projectors based on asymptotic scattering states. This allows to optimize final state distributions upon laser excitation in cases where strong non-adiabatic effects are present. The approach, despite being based on a time-local formulation, can take non-adiabatic transitions that appear at later times fully into account and adopt a corresponding control strategy. As an example, we show various dissociation channels of HeH+, a system where the ultrafast dissociationdynamics is determined by strong non-Born-Oppenheimer effects.
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Dates et versions

hal-00935181 , version 1 (23-01-2014)

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Laetitia Bomble, Aurélie Chenel, Christoph Meier, M. Desouter-Lecomte. Local control of non-adiabatic dissociation dynamics. The Journal of Chemical Physics, 2011, 134, pp.204112. ⟨10.1063/1.3589911⟩. ⟨hal-00935181⟩
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