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Article Dans Une Revue Inorganica Chimica Acta Année : 2012

Iron Piano-Stool Phosphine Complexes for Catalytic Hydrosilylation Reaction

Résumé

A family of six cyclopentadienyl-iron carbonyl complexes bearing phosphine ligands (PPh3, PMe2Ph and PCy3) with iodide or PF6 as a counter-anion were prepared and used as catalysts for the hydrosilylation of carbonyl derivatives. Aldehydes were reduced at 30 °C, using PMHS as the silane, whereas ketones were reduced at 70 °C using PhSiH3.

Domaines

Catalyse

Dates et versions

hal-00864821 , version 1 (23-09-2013)

Identifiants

Citer

Jianxia Zheng, Luis C Misal Castro, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Iron Piano-Stool Phosphine Complexes for Catalytic Hydrosilylation Reaction. Inorganica Chimica Acta, 2012, 380, pp.301-307. ⟨10.1016/j.ica.2011.10.048⟩. ⟨hal-00864821⟩
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