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Chapitre D'ouvrage Année : 2013

Paramagnetic Solid-State Magic-Angle Spinning NMR Spectroscopy

Guido Pintacuda
Gwendal Kervern

Résumé

A number of technical improvements have recently opened up solid-state NMR to the analysis of new classes of substrates with wide ranging implications for molecular and biological sciences, with an immediate impact on a large community of researchers. A wealth of information can be extracted from the analysis of solid-state NMR signals of paramagnetic compounds, as the changes induced by the paramagnetic center depend in a well-defined way on the structure of the molecule. Solid-state NMR is in a position to allow direct, straightforward experimental access to the fine details of the molecular electronic configuration, which is in turn a sensible reporter of the molecular geometry in small catalysts as well as in larger biomolecules

Dates et versions

hal-00860747 , version 1 (11-09-2013)

Identifiants

Citer

Guido Pintacuda, Gwendal Kervern. Paramagnetic Solid-State Magic-Angle Spinning NMR Spectroscopy. Heise, Henrike; Matthews, Stephen (Eds.). Modern NMR Methodology, Springer, pp.157-200, 2013, Topics in Current Chemistry, 978-3-642-37991-8. ⟨10.1007/128_2011_312⟩. ⟨hal-00860747⟩
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