MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification - Archive ouverte HAL
Article Dans Une Revue Journal of the American Chemical Society Année : 2013

MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

J. Canivet
S. Aguado
  • Fonction : Auteur
Y. Schuurman
D. Farrusseng

Résumé

The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.
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Dates et versions

hal-00826367 , version 1 (31-08-2020)

Identifiants

Citer

J. Canivet, S. Aguado, Y. Schuurman, D. Farrusseng. MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification. Journal of the American Chemical Society, 2013, 135 (11), pp.4195-4198. ⟨10.1021/ja312120x⟩. ⟨hal-00826367⟩
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