Soft-mode dynamics in micrograin and nanograin ceramics of strontium titanate observed by hyper-Raman scattering - Archive ouverte HAL
Article Dans Une Revue Physical Review B: Condensed Matter and Materials Physics (1998-2015) Année : 2013

Soft-mode dynamics in micrograin and nanograin ceramics of strontium titanate observed by hyper-Raman scattering

Résumé

The low-frequency vibrations of micro- and nanograin ceramics of strontium titanate are investigated by hyper-Raman spectroscopy. The combination of a confocal optical microscope with an ultranarrow Notch filter enabled an accurate spectroscopy on both the Stokes and anti-Stokes side down to about 8 cm−1. A splitting of the soft mode into E-u- and A-2u-symmetry vibrations is clearly observed in the micrograin sample. The peculiar temperature dependence of ω^2_A2u−ω^2_Eu emphasizes a nonlinear coupling between the square of the TiO6 tilting angle and the spontaneous strain c/a − 1. In addition, the very different temperature behavior of the linewidth of the two soft components is assigned to the growth of a disorder anisotropy on cooling, probably on the titanium site.
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Dates et versions

hal-00787294 , version 1 (11-02-2013)

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Citer

Bernard Hehlen, A. Al-Zein, Christine Bogicevic, P. Gemeiner, Jean-Michel Kiat. Soft-mode dynamics in micrograin and nanograin ceramics of strontium titanate observed by hyper-Raman scattering. Physical Review B: Condensed Matter and Materials Physics (1998-2015), 2013, 87, pp.014303. ⟨10.1103/PhysRevB.87.014303⟩. ⟨hal-00787294⟩
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