Quantification of Hydrogen Peroxide during the Low-Temperature Oxidation of Alkanes
Résumé
The first reliable quantification of hydrogen peroxide (H2O2) formed during the low-temperature oxidation of an organic compound has been achieved thanks to a new system that couples a jet stirred reactor to a detection by continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near-infrared. The quantification of this key compound for hydrocarbon low-temperature oxidation regime has been obtained under conditions close to those actually observed before the autoignition. The studied hydrocarbon was n-butane, the smallest alkane which has an oxidation behavior close to that of the species present in gasoline and diesel fuels.
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2012_CRDS_JACS.pdf (137.89 Ko)
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Supplemental_Data.pdf (384.6 Ko)
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| Origine | Fichiers produits par l'(les) auteur(s) |
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| Format | Autre |
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