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Communication Dans Un Congrès Année : 2001

Grafting polymers onto C-60 via an atom transfer reaction

F Audouin
  • Fonction : Auteur
Sandra Helias Nunige
R Nuffer
  • Fonction : Auteur
C Mathis
  • Fonction : Auteur

Résumé

Halogen terminated PS chains of low polydispersity, prepared by atom transfer radical polymerization (ATRP), can be converted to macro-radicals using an atom transfer reaction and so attached to C,,. Depending on the stoichiometry PS-Br/ C-60 2 or 4 chains are grafted onto the fullerene. We propose a mechanism which can explain that no adducts with an odd number of arms are formed.
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Dates et versions

hal-00709605 , version 1 (19-06-2012)

Identifiants

  • HAL Id : hal-00709605 , version 1

Citer

F Audouin, Sandra Helias Nunige, R Nuffer, C Mathis. Grafting polymers onto C-60 via an atom transfer reaction. 16th International Conference on Science and Technology of Synthetic Metals (ICSM 2000), Jul 2000, GASTEIN (AUSTRIA), France. pp.1149-1150. ⟨hal-00709605⟩
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