New Hybrid Membranes Based on Phosphonic Acid Functionalized Silica Particles for PEMFC - Archive ouverte HAL
Article Dans Une Revue Journal of Polymer Science Part A: Polymer Chemistry Année : 2012

New Hybrid Membranes Based on Phosphonic Acid Functionalized Silica Particles for PEMFC

Résumé

This work concerns the development of hybrid organic/ inorganic membranes from styrenic phosphonic polymers. The phosphonic charge, composed phosphonic polymers grafted onto silica nanoparticles, was obtained by ''grafting onto'' method. It consists of synthesizing first the polymer, and then the terminal functions of the latter react with silanol groups of silica. The phosphonated polymer was isolated in two steps, that is, an ATRP polymerization of 4- chloromethylstyrene followed by Mickaelı¨s-Arbusov reaction. After the grafting onto silica, membranes are prepared through formulation containing the charge and the polymer matrix PVDF-HFP, which are dispersed in DMF. The acid form is obtained by hydrolysis in chlorydric acid. The membrane possessing a 40 wt % charge ratio (IEC ¼ 1.08 meq g 1) was selected as reference. A proton conductivity of 65 mS cm 1 at 80 C was measured in immersed conditions. When the membrane is no more immersed, the value decreases drastically (0.21 mS cm 1 at 120 C and 25% RH).

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Polymères

Dates et versions

hal-00657203 , version 1 (06-01-2012)

Identifiants

Citer

Ghislain David, Etienne Labalme, Pierrick Buvat, Jannick Bigarre, Thomas Boucheteau. New Hybrid Membranes Based on Phosphonic Acid Functionalized Silica Particles for PEMFC. Journal of Polymer Science Part A: Polymer Chemistry, 2012, 50, pp.1308-1316. ⟨10.1002/pola.25895⟩. ⟨hal-00657203⟩
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