Article Dans Une Revue Chemical Communications Année : 2011

The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2*nH2O (with n = 2) spin crossover compound proven by single crystal investigations

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The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)3]X2*nH2O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, X = NO3 and n = 2. This study definitively proves the 1-D polymeric nature of the crystal structure and allows a description of the [Fe(Rtrz)3] chains, as well as of the anions and water implementation within the crystal lattice opening the possibility of subsequent investigations of the structure-property correlation within this peculiar family of spin transition compounds.

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hal-00641727 , version 1 (13-03-2025)

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Arnaud Grosjean, Nathalie Daro, Brice Kauffmann, Abdellah Kaiba, Jean-François Létard, et al.. The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2*nH2O (with n = 2) spin crossover compound proven by single crystal investigations. Chemical Communications, 2011, 47 (45), pp.12382-12384. ⟨10.1039/C1CC14220H⟩. ⟨hal-00641727⟩
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