Tyre-road estimation methods have been the objective of many research programmes throughout the world. Most of these methods aim at estimating the friction components such as tyre longitudinal slip rate κ and friction coefficient μ in the contact patch area. In order to estimate the maximum available friction coefficient μmax , these methods generally use a probabilistic relationship between the grip obtained for low tyre excitations (such as constant speed driving) and the grip obtained for high tyre excitations (such as emergency braking manoeuvre). Confirmation or invalidation of this relationship from experimental results is the purpose of this paper. Experiments have been carried out on a reference track including several test boards corresponding to a wide textural spectrum. The main advantage of these experiments lies in the use of a vehicle allowing us to accurately build point-by-point relationship between κ and μ. This relationship has been determined for different tyres and pavement textures. Finally, the curves obtained are analysed to check the validity of the relationship between the current friction coefficient used by the car during normal driving conditions and μmax.