Experimental Confirmation of the Low-Temperature Oxidation Scheme of Alkanes
Résumé
Intermediate detected: The design of internal combustion engines relies on a good understanding of the mechanism of the auto-ignition of hydrocarbons. A key assumption of this mechanism, which was commonly accepted but never proven, has now been experimentally demonstrated: the formation of ketohydroperoxides has been observed under conditions close to those actually observed before the auto-ignition.
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2010_keto_AngChem.pdf (330.9 Ko)
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Supplemental_data.pdf (433.28 Ko)
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| Origine | Fichiers produits par l'(les) auteur(s) |
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| Format | Autre |
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