<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-00588863</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-03T06:54:20+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Croconato-containing M(III) (M = Ga, Er) complexes as potential building blocks for mono/multifunctional molecular materials</title>
            <author role="aut">
              <persName>
                <forename type="first">Flavia</forename>
                <surname>Artizzu</surname>
              </persName>
              <idno type="halauthorid">496804-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Paola</forename>
                <surname>Deplano</surname>
              </persName>
              <idno type="halauthorid">496809-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Luca</forename>
                <surname>Pilia</surname>
              </persName>
              <idno type="halauthorid">496807-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Angela</forename>
                <surname>Serpe</surname>
              </persName>
              <idno type="halauthorid">496808-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Luciano</forename>
                <surname>Marchio</surname>
              </persName>
              <idno type="halauthorid">496805-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Kevin</forename>
                <surname>Bernot</surname>
              </persName>
              <email type="md5">fa731869444f50ee594b6542b885a8fc</email>
              <email type="domain">insa-rennes.fr</email>
              <ptr type="url" target="https://iscr-csm.insa-rennes.fr/kevinbernot/"/>
              <idno type="idhal" notation="string">kevinbernot</idno>
              <idno type="idhal" notation="numeric">171068</idno>
              <idno type="halauthorid" notation="string">19475-171068</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-8337-6246</idno>
              <idno type="IDREF">https://www.idref.fr/197317073</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=expPZ5AAAAAJ</idno>
              <affiliation ref="#struct-194938"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Maria-Laura</forename>
                <surname>Mercuri</surname>
              </persName>
              <idno type="halauthorid">496806-0</idno>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Isabelle</forename>
                <surname>Morlais</surname>
              </persName>
              <email type="md5">04e79c6cef58e93dcad2950644e43463</email>
              <email type="domain">insa-rennes.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2011-04-26 17:12:48</date>
              <date type="whenModified">2025-07-01 15:04:02</date>
              <date type="whenReleased">2011-04-26 17:12:48</date>
              <date type="whenProduced">2011</date>
              <ref type="externalLink" target="https://api.istex.fr/ark:/67375/6H6-46FHLC63-J/fulltext.pdf?sid=hal"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="149396">
                <persName>
                  <forename>Isabelle</forename>
                  <surname>Morlais</surname>
                </persName>
                <email type="md5">04e79c6cef58e93dcad2950644e43463</email>
                <email type="domain">insa-rennes.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-00588863</idno>
            <idno type="halUri">https://hal.science/hal-00588863</idno>
            <idno type="halBibtex">artizzu:hal-00588863</idno>
            <idno type="halRefHtml">&lt;i&gt;Inorganica Chimica Acta&lt;/i&gt;, 2011, 370, pp.471-481. &lt;a target="_blank" href="https://dx.doi.org/10.1016/j.ica.2011.02.023"&gt;&amp;#x27E8;10.1016/j.ica.2011.02.023&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Inorganica Chimica Acta, 2011, 370, pp.471-481. &amp;#x27E8;10.1016/j.ica.2011.02.023&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="UNIV-RENNES1">Université de Rennes 1</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="INSA-RENNES">Institut National des Sciences Appliquées de Rennes</idno>
            <idno type="stamp" n="ENSC-RENNES">Ecole Nationale Supérieure de Chimie de Rennes</idno>
            <idno type="stamp" n="SCR-MI-INSA" corresp="INSA-RENNES">Sciences Chimiques de Rennes Equipe Chimie du Solide et Matériaux</idno>
            <idno type="stamp" n="ISCR">INSTITUT DES SCIENCES CHIMIQUES DE RENNES</idno>
            <idno type="stamp" n="SCR_CTI">Chimie Théorique Inorganique</idno>
            <idno type="stamp" n="SCR-CSM" corresp="ISCR">Chimie du Solide et Matériaux</idno>
            <idno type="stamp" n="ISCR-CSM" corresp="ISCR">Chimie du Solide et Matériaux</idno>
            <idno type="stamp" n="UR1-SPM">Université de Rennes 1 - UFR Sciences et Propriétés de la Matière</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="UR1-UFR-SPM">UFR SPM Sciences et Propriétés de la Matière</idno>
            <idno type="stamp" n="UR1-HAL">Publications labos UR1 dans HAL-Rennes 1</idno>
            <idno type="stamp" n="UR1-SDLM">UR1 - publications SDLM</idno>
            <idno type="stamp" n="TEST-UNIV-RENNES">TEST Université de Rennes</idno>
            <idno type="stamp" n="TEST-UR-CSS">TEST Université de Rennes CSS</idno>
            <idno type="stamp" n="UNIV-RENNES">Université de Rennes</idno>
            <idno type="stamp" n="INSA-GROUPE">Groupe INSA</idno>
            <idno type="stamp" n="ISCR-CSM-INSA" corresp="ISCR">Sciences chimiques de Rennes / équipe Chimie du Solide et Matériaux - site INSA Rennes</idno>
            <idno type="stamp" n="UR1-MMS">Pôle UnivRennes - Matériaux</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Croconato-containing M(III) (M = Ga, Er) complexes as potential building blocks for mono/multifunctional molecular materials</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Flavia</forename>
                    <surname>Artizzu</surname>
                  </persName>
                  <idno type="halauthorid">496804-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Paola</forename>
                    <surname>Deplano</surname>
                  </persName>
                  <idno type="halauthorid">496809-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Luca</forename>
                    <surname>Pilia</surname>
                  </persName>
                  <idno type="halauthorid">496807-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Angela</forename>
                    <surname>Serpe</surname>
                  </persName>
                  <idno type="halauthorid">496808-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Luciano</forename>
                    <surname>Marchio</surname>
                  </persName>
                  <idno type="halauthorid">496805-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Kevin</forename>
                    <surname>Bernot</surname>
                  </persName>
                  <email type="md5">fa731869444f50ee594b6542b885a8fc</email>
                  <email type="domain">insa-rennes.fr</email>
                  <ptr type="url" target="https://iscr-csm.insa-rennes.fr/kevinbernot/"/>
                  <idno type="idhal" notation="string">kevinbernot</idno>
                  <idno type="idhal" notation="numeric">171068</idno>
                  <idno type="halauthorid" notation="string">19475-171068</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-8337-6246</idno>
                  <idno type="IDREF">https://www.idref.fr/197317073</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=expPZ5AAAAAJ</idno>
                  <affiliation ref="#struct-194938"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Maria-Laura</forename>
                    <surname>Mercuri</surname>
                  </persName>
                  <idno type="halauthorid">496806-0</idno>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">14221</idno>
                <idno type="issn">0020-1693</idno>
                <idno type="eissn">0020-1693</idno>
                <title level="j">Inorganica Chimica Acta</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">370</biblScope>
                  <biblScope unit="pp">471-481</biblScope>
                  <date type="datePub">2011</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1016/j.ica.2011.02.023</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Material science Gallium Lanthanides Magnetic properties Vibrational spectroscopy</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.inor">Chemical Sciences/Inorganic chemistry</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>The one-pot synthesis and structural characterization of two new complexes of the croconato ligand (C5O5)2 with the Ga(III) and Er(III) metal ions are reported. The mononuclear tris-chelated (n-Bu4N)3[- Ga(C5O5)3], 1, which exhibits an octahedral geometry, is present as D and K enantiomers in equal amounts; the K2[Er(C5O5)(l-SO4)(OH2)4]2 complex, 2, shows dinuclear erbium moieties with bridging sulfate anions and interposed K(I) cations with a capped trigonal prismatic coordination geometry. 2 shows paramagnetic behavior in the 2-300 K range typical of two isolated Er(III) ions. Vibrational (FTIR and FT-Raman) and electronic spectroscopies have shown to be a reliable diagnostic tool in distinguishing different molecular arrangements of the croconato ligand in different complexes. The analogies of the gallium complex with the corresponding [M(C2O4)3]3 tris-chelated complexes which have been used as chiral building blocks of molecular conductors are pointed out.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-194938" status="VALID">
          <idno type="IdRef">161775241</idno>
          <idno type="ISNI">0000 0004 0385 6584</idno>
          <idno type="RNSR">200612270R</idno>
          <idno type="ROR">https://ror.org/00adwkx90</idno>
          <idno type="Wikidata">Q30261343</idno>
          <orgName>Institut des Sciences Chimiques de Rennes</orgName>
          <orgName type="acronym">ISCR</orgName>
          <date type="start">2006-01-01</date>
          <desc>
            <address>
              <addrLine>Campus de Beaulieu - Bât. 10 Avenue du Général Leclerc 35042 Rennes Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://iscr.univ-rennes.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-105160" type="direct"/>
            <relation active="#struct-117606" type="direct"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation active="#struct-300373" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR6226" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-105160" status="VALID">
          <idno type="IdRef">26693823X</idno>
          <idno type="ROR">https://ror.org/015m7wh34</idno>
          <orgName>Université de Rennes</orgName>
          <orgName type="acronym">UR</orgName>
          <desc>
            <address>
              <addrLine>Campus de Beaulieu, 263 avenue Général Leclerc, CS 74205, 35042 RENNES CEDEX</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-rennes.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-117606" status="VALID">
          <idno type="ROR">https://ror.org/04xaa4j22</idno>
          <orgName>Institut National des Sciences Appliquées - Rennes</orgName>
          <orgName type="acronym">INSA Rennes</orgName>
          <desc>
            <address>
              <addrLine>20, avenue des Buttes de Coësmes - CS 70839 - 35708 Rennes cedex 7</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insa-rennes.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301232" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301232" status="VALID">
          <idno type="IdRef">162105150</idno>
          <orgName>Institut National des Sciences Appliquées</orgName>
          <orgName type="acronym">INSA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300373" status="VALID">
          <idno type="ROR">https://ror.org/01h0ffh48</idno>
          <orgName>Ecole Nationale Supérieure de Chimie de Rennes</orgName>
          <orgName type="acronym">ENSCR</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>