Effect of Water Adsorption on Ion Dynamics in Confined Geometry: Na+-Faujasites and Homoionic Alkali Exchanged Montmorillonite
Résumé
Various experimental and molecular simulation methods are used to investigate water adsorption and its related effects on ion dynamics in two typical examples of microporous solids: Na+-Faujasites and homoionic alkali exchanged montmorillonites. Influence of the confinement, of the cationic density and of the cation size is examined. It is then shown that all these parameters play a key role in water adsorption thermodynamics and in the cation/water subsystem dynamics.
Domaines
Chimie théorique et/ou physiqueOrigine | Fichiers produits par l'(les) auteur(s) |
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